F
Frank W. Heinemann
Researcher at University of Erlangen-Nuremberg
Publications - 453
Citations - 11119
Frank W. Heinemann is an academic researcher from University of Erlangen-Nuremberg. The author has contributed to research in topics: Ligand & Crystal structure. The author has an hindex of 50, co-authored 438 publications receiving 10017 citations. Previous affiliations of Frank W. Heinemann include University of California, San Diego & University of Freiburg.
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Journal ArticleDOI
Copper–Nitrene Complexes in Catalytic C ? H Amination
Yosra M. Badiei,Adriana Dinescu,Xuliang Dai,Robert M. Palomino,Frank W. Heinemann,Thomas R. Cundari,Timothy H. Warren +6 more
TL;DR: Several catalytic protocols based on Rh, Ru, Ag, Au, Cu, and other metals for the amination of benzylic or allylic C H bonds with iminoiodanes bearing electrondeficient N substituents represent useful methodologies for the transformation of C H into C N bonds.
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Synthesis, structure, and reactivity of an iron(V) nitride.
Jeremiah J. Scepaniak,Carola S. Vogel,Marat M. Khusniyarov,Frank W. Heinemann,Karsten Meyer,Jeremy M. Smith +5 more
TL;DR: Mößbauer and electron paramagnetic resonance spectroscopic characterization, supported by electronic structure calculations, provide evidence for a d3 iron(V) metal center in a low spin (S = 1/2) electron configuration.
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A Mononuclear Fe(III) Single Molecule Magnet with a 3/2↔5/2 Spin Crossover
Susanne Mossin,Ba L. Tran,Debashis Adhikari,Maren Pink,Frank W. Heinemann,Jörg Sutter,Robert K. Szilagyi,Karsten Meyer,Daniel J. Mindiola +8 more
TL;DR: Multiedge XAS absorption spectra suggest the electronic structure of 1 to be highly covalent with an effective iron oxidation state that is more reduced than the typical ferric complexes due to the significant interaction of the phosphine groups in PNP and Cl ligands with iron.
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Carbon dioxide activation with sterically pressured mid- and high-valent uranium complexes.
Suzanne C. Bart,Christian Anthon,Frank W. Heinemann,Eckhard Bill,Norman M. Edelstein,Karsten Meyer +5 more
TL;DR: The molecular structures of the synthesized uranium carbamate complexes highlight the different reactivities due to the steric pressure introduced by the alkyl derivatized tris(aryloxide) triazacyclononane ligand.
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An Iron Nitride Complex
TL;DR: The synthesis, spectroscopy, and X-ray diffraction analysis of a discrete iron nitride complex stabilized by the sterically encumbering Nanchored tris(carbene) ligand are presented, enabling the first room-temperature spectroscopic characterization of a terminal Fe nitride species.