G
George M. Sheldrick
Researcher at University of Göttingen
Publications - 794
Citations - 170469
George M. Sheldrick is an academic researcher from University of Göttingen. The author has contributed to research in topics: Crystal structure & Molecule. The author has an hindex of 58, co-authored 791 publications receiving 151229 citations. Previous affiliations of George M. Sheldrick include University of Regensburg.
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Journal ArticleDOI
Sterically crowded cyclohexanes-2 synthesis, structure and dynamics of hexaspiro[2.0.3.0.2.0.3.0.2.0.3.0]heneicosane
LutzFitjer,Ulrich Klages,Walter Kuhn,David S. Stephenson,Gerhard Binsch,Mathias Noltemeyer,Ernst Egert,George M. Sheldrick +7 more
TL;DR: In this paper, the synthesis, structure and dynamics of hexaspiro[2.0.2.3.0]-heneicosane 3 are described, which adopts a chair conformation in the crystal state but prefers a chair-to-twistboat equilibrium in solution.
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Novel compounds with gold–transition–metal bonds; crystal and molecular structure of bis(triphenylphosphine)iminium bis(tetracarbonylcobaltio)aurate(I)
TL;DR: In this paper, the tetrahydrothiophen group (tht) in [Au(C6F5)3(tht)] can readily be replaced by carbonylmetallate anions [M(Co)n] or [NBun4] whose reactivity with PPh3 depends upon M.
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Darstellung und Struktur von Thallium(I)‐2,4,6‐tris(trifluormethyl)thiophenolat, einer Verbindung mit faltblattartig‐polymerem Aufbau
Dieter Labahn,Ehmke Phol,Regine Herbst-Irmer,Dietmar Stalke,Herbert W. Roesky,George M. Sheldrick +5 more
TL;DR: A single X-ray structural analysis shows a folded polymeric structure for thallium(I) 2,4,6-tris(trifluoromethyl)thiophenolate as mentioned in this paper.
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Towards [6.5]coronane - fivefold cyclobutylmethyl-cyclopentyl rearrangement in a pentaspiroheneicosanal
TL;DR: In this article, the synthesis and successful rearrangement of the pentaspirane 4 yields the hexacyclic 11, whose stereochemistry was unequivocally established as all- cis by X-ray analysis of a single epoxide derived therefrom.
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Highly diastereoselective synthesis of 1,2-epoxy-4-hydroxyalkyl carbamates. Masked and activated α,γ-dihydroxy-alkanals and -alkanones
TL;DR: (Z )-anti-4-hydroxy-1-alkenyl carbamates 1 yield, with essentially complete diastereoselectivity, for the epoxides 2 with (1 Z -2-3- anti-3, 4, 4 anti-configuration on treatment with tert -butylhydroperoxide/vanadylbis(acetoacetonate) as mentioned in this paper.