G
Georgina M. Rosair
Researcher at Heriot-Watt University
Publications - 236
Citations - 5951
Georgina M. Rosair is an academic researcher from Heriot-Watt University. The author has contributed to research in topics: Crystal structure & Carborane. The author has an hindex of 36, co-authored 232 publications receiving 5484 citations.
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Journal ArticleDOI
The synthesis and characterisation of 4,1,2-MC2B10 metallacarboranes
Ruaraidh D. McIntosh,David Ellis,Javier Gil-Lostes,Kelly J. Dalby,Georgina M. Rosair,Alan J. Welch +5 more
TL;DR: Low-temperature experiments on the more soluble platinacarborane could not freeze out the diamond-trapezium-diamond fluctional process that the authors assume is operating in solution, and it is concluded that this process has a relatively low activation barrier.
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Synthesis, crystal structures and magnetic studies of dicyanamide bridged two new 1D copper(II) complexes
TL;DR: In this paper, two dicyanamide bridged 1D polynuclear copper(II) complexes have been synthesized and structures of both the complexes and their crystal packing arrangements have been established by X-ray crystallography.
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The first examples of η5-bonding of a carbaborylphosphine ligand to transition metals. Synthesis and characterisation of 7-{PPh2AuPPh3}-8-Ph-7,8-nido-C2B9H10, 1-{PPh2AuCl}-2-Ph-3-(p-cymene)-3,1,2-pseudocloso-RuC2B9H9 and 1-{PPh2AuCl}-2-Ph-3-(η-C5Me5)-3,1,2-pseudocloso-RhC2B9H9,
TL;DR: In this article, the closo carbaborylmonophosphine 1-PPh2-2-Ph-1,2-closo-C2B10H10 is deboronated by reaction with ClAuPPh3 in refluxing ethanol to afford the zwitterionic compound 7-{PPh 2AuPsPh3}-8-Ph7,8-nido-C 2B9H10, characterised by NMR spectroscopy and X-ray crystallography.
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Silver Effect in Regiodivergent Gold-Catalyzed Hydroaminations
TL;DR: In this paper, it was shown that the use of silver as halide abstractors in gold-catalyzed reactions may result in "silver effects" when terminal alkyne substrates are involved.
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Unusually Weak Binding Interactions in Tetrazole−Amidine Complexes
TL;DR: Crystal structures revealed that the N...H-N hydrogen bonds in amidinium tetrazolates are bent and noticeably longer than corresponding hydrogen Bonds in both Amidinium carboxylates and ammonium tetazolates.