H
Hermas R. Jiménez
Researcher at University of Valencia
Publications - 41
Citations - 614
Hermas R. Jiménez is an academic researcher from University of Valencia. The author has contributed to research in topics: Nuclear magnetic resonance spectroscopy & Azurin. The author has an hindex of 16, co-authored 41 publications receiving 580 citations. Previous affiliations of Hermas R. Jiménez include Curie Institute.
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Journal ArticleDOI
A Ferromagnetic [Cu3(OH)2]4+ Cluster Formed inside a Tritopic Nonaazapyridinophane: Crystal Structure and Solution Studies†
Almudena González-Álvarez,Ignacio Alfonso,Juan Cano,Pilar Díaz,Vicente Gotor,Vicente Gotor-Fernández,Enrique García-España,Santiago García-Granda,Hermas R. Jiménez,Francesc Lloret +9 more
TL;DR: Small-molecule studies aimed at mimicking the properties of trinuclear Cu centers, which have attracted great interest from both the biochemical and magnetochemical points of view, are of great relevance.
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Binuclear Cu2+ complex mediated discrimination between L-glutamate and L-aspartate in water.
Begoña Verdejo,Juan A. Aguilar,Antonio Doménech,Carlos Miranda,Pilar Navarro,Hermas R. Jiménez,Conxa Soriano,Enrique García-España +7 more
TL;DR: L-glutamate and L-aspartate selectivity is achieved by the action of two Cu2+ metal ions rightly disposed in a cyclophane-type macrocyclic framework.
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Imidazolate bridged Cu(II)-Cu(II) and Cu(II)-Zn(II) complexes of a terpyridinophane azamacrocycle: a solution and solid state study.
Begoña Verdejo,Salvador Blasco,Enrique García-España,Francisco Lloret,Pablo Gaviña,Conxa Soriano,Sergio Tatay,Hermas R. Jiménez,Antonio Doménech,Julio Latorre +9 more
TL;DR: UV-Vis spectroscopy and paramagnetic NMR data show that imidazole coordinates to the Cu2+ ions as a bridgingImidazolate ligand from pH 5 to 10, and the apparent stability constant obtained at pH = 9 for the addition of imidrazole to the dinuclear Cu2-Zn2+ complexes is one of the highest so far reported.
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EPR and Magnetic Susceptibility Studies of Cobalt(II)- and Nickel(II)-Substituted Azurins from Pseudomonas aeruginosa. Electronic Structure of the Active Sites
TL;DR: In this article, the electronic properties of cobalt and nickel-substituted azurins from Pseudomonas aeruginosa have been investigated and the EPR spectrum of Co(II)−azurin shows the typical pattern of a Kramers' doublet associated with an S = 3/2 ground state in a distorted axial symmetry environment.
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Paramagnetic cobalt and nickel derivatives of alcaligenes denitrificans azurin and its m121q mutant. a 1h nmr study
Jesús Salgado,Hermas R. Jiménez,José M. Moratal,Sandra J. Kroes,Gertrud C. M. Warmerdam,Gerard W. Canters +5 more
TL;DR: The similarity between the NMR spectra of the Co(II) derivatives of stellacyanin and the M121Q azurin is in agreement with a very similar metal site in both proteins and supports the existence of a coordinated Gln in stellACYanin.