H
Hongyin Gao
Researcher at Shandong University
Publications - 41
Citations - 1566
Hongyin Gao is an academic researcher from Shandong University. The author has contributed to research in topics: Catalysis & Regioselectivity. The author has an hindex of 17, co-authored 41 publications receiving 1330 citations. Previous affiliations of Hongyin Gao include Brigham Young University & University of Texas Southwestern Medical Center.
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Journal ArticleDOI
Direct Stereospecific Synthesis of Unprotected N-H and N-Me Aziridines from Olefins
Jawahar L. Jat,Mahesh P. Paudyal,Hongyin Gao,Qing-Long Xu,Muhammed Yousufuddin,Deepa Devarajan,Daniel H. Ess,Lászĺo K̈urti,John R. Falck +8 more
TL;DR: A mild, versatile method for the direct stereospecific conversion of structurally diverse mono-, di-, tri-, and tetrasubstituted olefins to N-H aziridines using O-(2,4-dinitrophenyl)hydroxylamine (DPH) via homogeneous rhodium catalysis with no external oxidants is presented.
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Organocatalytic aryl-aryl bond formation: An atroposelective [3,3]-rearrangement approach to BINAM derivatives
TL;DR: Density functional calculations reveal that, in the transition state for C-C bond formation, the phosphoric acid proton of the catalyst is fully transferred to one of the N-atoms of the substrate, and the resulting phosphate acts as a chiral counterion.
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Rapid synthesis of fused N-heterocycles by transition-metal-free electrophilic amination of arene C-H bonds.
TL;DR: An efficient and operationally simple protocol for the preparation of fused N-heterocycles starting from readily available 2-nitrobiaryls and PhMgBr under mild conditions is disclosed.
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Practical Organocatalytic Synthesis of Functionalized Non‐C2‐Symmetrical Atropisomeric Biaryls
TL;DR: Density-functional calculations suggest that the quinone and imino-quinone monoacetal coupling partners are exclusively arylated at their α-position by an asynchronous [3,3]-sigmatropic rearrangement of a mixed acetal species which is formed in situ under the reaction conditions.