The chemistry of graphene oxide is discussed in this critical review Particular emphasis is directed toward the synthesis of graphene oxide, as well as its structure Graphene oxide as a substrate for a variety of chemical transformations, including its reduction to graphene-like materials, is also discussed This review will be of value to synthetic chemists interested in this emerging field of materials science, as well as those investigating applications of graphene who would find a more thorough treatment of the chemistry of graphene oxide useful in understanding the scope and limitations of current approaches which utilize this material (91 references)

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The chemistry of graphene oxide

There is intense interest in graphene in fields such as physics, chemistry, and materials science, among others. Interest in graphene's exceptional physical properties, chemical tunability, and potential for applications has generated thousands of publications and an accelerating pace of research, making review of such research timely. Here is an overview of the synthesis, properties, and applications of graphene and related materials (primarily, graphite oxide and its colloidal suspensions and materials made from them), from a materials science perspective.

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Graphene and Graphene Oxide: Synthesis, Properties, and Applications

Electrochemical energy storage technology is based on devices capable of exhibiting high energy density (batteries) or high power density (electrochemical capacitors). There is a growing need, for current and near-future applications, where both high energy and high power densities are required in the same material. Pseudocapacitance, a faradaic process involving surface or near surface redox reactions, offers a means of achieving high energy density at high charge–discharge rates. Here, we focus on the pseudocapacitive properties of transition metal oxides. First, we introduce pseudocapacitance and describe its electrochemical features. Then, we review the most relevant pseudocapacitive materials in aqueous and non-aqueous electrolytes. The major challenges for pseudocapacitive materials along with a future outlook are detailed at the end.

https://hal.archives-ouvertes.fr/hal-01171774/document

Pseudocapacitive oxide materials for high-rate electrochemical energy storage

Every few years, a new material with unique properties emerges and fascinates the scientific community, typical recent examples being high-temperature superconductors and carbon nanotubes. Graphene is the latest sensation with unusual properties, such as half-integer quantum Hall effect and ballistic electron transport. This two-dimensional material which is the parent of all graphitic carbon forms is strictly expected to comprise a single layer, but there is considerable interest in investigating two-layer and few-layer graphenes as well. Synthesis and characterization of graphenes pose challenges, but there has been considerable progress in the last year or so. Herein, we present the status of graphene research which includes aspects related to synthesis, characterization, structure, and properties.

Graphene: The New Two-Dimensional Nanomaterial

Graphene has attracted tremendous research interest in recent years, owing to its exceptional properties. The scaled-up and reliable production of graphene derivatives, such as graphene oxide (GO) and reduced graphene oxide (rGO), offers a wide range of possibilities to synthesize graphene-based functional materials for various applications. This critical review presents and discusses the current development of graphene-based composites. After introduction of the synthesis methods for graphene and its derivatives as well as their properties, we focus on the description of various methods to synthesize graphene-based composites, especially those with functional polymers and inorganic nanostructures. Particular emphasis is placed on strategies for the optimization of composite properties. Lastly, the advantages of graphene-based composites in applications such as the Li-ion batteries, supercapacitors, fuel cells, photovoltaic devices, photocatalysis, as well as Raman enhancement are described (279 references).

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Graphene-based composites

https://onlinelibrary.wiley.com/doi/pdf/10.1002/aenm.201970050

Micro‐Supercapacitors: Hydrous RuO2‐Decorated MXene Coordinating with Silver Nanowire Inks Enabling Fully Printed Micro‐Supercapacitors with Extraordinary Volumetric Performance (Adv. Energy Mater. 15/2019)

The Feasibility of Healable Electronics and Mechanical Behavior of Silver Nanowire (AgNW)/Healable Polymer Composite

The invention provides a preparation method and application of conductive ink based on metal nanowire and graphene oxide. The graphene oxide is simultaneously used as a dispersing agent, a thickening agent and a stabilizing agent. The metal nanowire, the graphene oxide, the deionized water, the alcohol solvent, the dispersing agent, the surface active agent, the flatting agent and the de-foaming agent are uniformly mixed at a certain mass ratio, so as to acquire the conductive ink product. The acquired ink can be directly written or printed on various substrate materials so as to construct a conductive circuit with high conductivity, stability, flexibility and high adhesion; the constructed conductive circuit is dried for 3-10 minutes under room temperature, so that ultrahigh conductivity is achieved; furthermore, the graphene oxide is reduced and the metal nanowire is sintered according to the methods, such as, selecting sintering temperature at 50-200 DEG C or performing chemical reduction under room temperature or utilizing an xenon flashlight to sinter, so that the conductivity of the conductive circuit is further increased.

Preparation method and application of conductive ink based on metal nanowire and graphene oxide

A thin-film field-effect transistor (TFT) is a three-terminal device comprising source, drain, and gate electrodes, a dielectric layer, a semiconductor layer, and a substrate. The TFT is a fundamental building component in a variety of electronic devices. Developing an intrinsically stretchable TFT entails availability and usage of a functional material with elastomeric deformability in response to an externally applied stress. This represents a major materials challenge. In this article, we survey strategies to synthesize these elastomeric functional materials, and how these materials are assembled to fabricate intrinsically stretchable TFT devices. Developing solution-based printing technology to assemble intrinsically stretchable TFTs is considered a prospective strategy for wearable electronics for industrial adaptation in the near future.

Intrinsically stretchable field-effect transistors

Composites of acrylonitrile butadiene styrene (ABS), epoxy and soluble cross-linked polyurethane (SCPU) with various loadings of single-walled carbon nanotubes (SWCNTs) were prepared. Their electromagnetic interference (EMI) shielding effectiveness (SE) in the frequency range of 8.2-12.4 GHz (X band) was studied. Well-dispersed SWCNT composites were created in these three representative polymer matrixes. The choice of polymer matrix greatly affects the conductivity, percolation threshold, and EMI shielding properties of the SWCNT/polymer composites. Enhanced EMI SE performances were observed for the composites with better dispersed SWCNTs. Moreover, the EMI SE performances strongly correlated with SWCNT loading in the polymer matrix. The best SWCNT dispersion was achieved in the epoxy matrix: 20-30 dB EMI SE was obtained with 15 wt% SWCNTs.

Jiajie Liang

Papers

Micro‐Supercapacitors: Hydrous RuO2‐Decorated MXene Coordinating with Silver Nanowire Inks Enabling Fully Printed Micro‐Supercapacitors with Extraordinary Volumetric Performance (Adv. Energy Mater. 15/2019)

The Feasibility of Healable Electronics and Mechanical Behavior of Silver Nanowire (AgNW)/Healable Polymer Composite

Preparation method and application of conductive ink based on metal nanowire and graphene oxide

Intrinsically stretchable field-effect transistors

Impact of polymer matrix on the electromagnetic interference shielding performance for single-walled carbon nanotubes-based composites.