Jianzhuang Jiang

TL;DR: A scalable general bottom-up approach to facilely synthesize ultrathin two-dimensional (2D) covalent organic framework (COF) nanosheets in large scale and high yield via an imine-exchange synthesis strategy through adding large excess amount of 2,4,6-trimethylbenzaldehyde into the reaction system under solvothermal condition.

TL;DR: In this article, the authors focus on the structure and function relationships of sandwich tetrapyrrole lanthanide compounds and their surface effect on the SMM properties of multikis(tetrapyryrrole) lanthanides.

TL;DR: Most of the effects of peripheral and nonperipheral substitution and changes in the ring (pi-conjugated system) size on the electrochemistry of metal-free phthalocyanines can be reasonably explained by considering the energy levels of frontier molecular orbitals of the corresponding compounds, which were obtained by calculations using the semiempirical PM3 method.

TL;DR: The present result appears to represent the first effort toward realization of controlling and tuning the morphology of self-assembled nanostructures of sandwich tetrapyrrole rare earth complexes through molecular design and synthesis.

TL;DR: By simple recrystallization, the catalytic activity of deactivated species can be recovered from the isolation yield 46% to 92% for 4-bromobenzonitrile conversion at the same conditions, revealing the great application potentials of HOF-based catalysts.