Joanna L. DiNaro

TL;DR: In this paper, uncertainty analysis is applied to a supercritical water hydrogen oxidation mechanism to determine the effect of uncertainties in reaction rate constants and species thermochemistry on predicted species concentrations, with all other model parameters and inputs treated as deterministic quantities.

TL;DR: In this article, the use of laboratory-scale equipment to measure intrinsic oxidation kinetics in supercritical water environments was evaluated, and no statistically significant difference was observed in the reaction rates or product distributions for the use either dissolved oxygen gas or hydrogen peroxide that was preheated and fully decomposed before mixing with methanol.

TL;DR: In this paper, the Rice−Ramsperger−Kassel theory was used to calculate the rate coefficients and, hence, product selectivities for pressure dependent reactions in supercritical water (SCW) benzene oxidation data.

TL;DR: In this paper, the authors examined the performance of thiodiglycol (HOC 2 H 4 ) 2 S over temperatures ranging from 100 to 525°C at a pressure of approximately 250 bar.

TL;DR: In this paper, the authors investigated the reactions of benzene in supercritical water and found that little to no reaction occurred without oxygen at temperatures between 530 and 625°C for residence times up to 6 s. The primary oxidation product at all reaction conditions studied was carbon dioxide.