J
John F. Stanton
Researcher at University of Florida
Publications - 25
Citations - 508
John F. Stanton is an academic researcher from University of Florida. The author has contributed to research in topics: Isomerization & Rotational–vibrational spectroscopy. The author has an hindex of 12, co-authored 25 publications receiving 407 citations. Previous affiliations of John F. Stanton include Harvard University & University of Texas at Austin.
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Journal ArticleDOI
Spontaneous and Selective Formation of HSNO, a Crucial Intermediate Linking H2S and Nitroso Chemistries
Matthew Nava,Marie-Aline Martin-Drumel,Christopher A. Lopez,Kyle N. Crabtree,Caroline C. Womack,Thanh L. Nguyen,Sven Thorwirth,Christopher C. Cummins,John F. Stanton,Michael C. McCarthy +9 more
TL;DR: It is established that HSNO is spontaneously formed in high concentration when NO and H2S gases are mixed at room temperature in the presence of metallic surfaces and the length of the S-N bond is found to be unusually long: 1.84 Å.
Journal ArticleDOI
The Molecular Structure of gauche‐1,3‐Butadiene: Experimental Establishment of Non‐planarity
Joshua H. Baraban,Joshua H. Baraban,Marie-Aline Martin-Drumel,Marie-Aline Martin-Drumel,P. Bryan Changala,Sandra Eibenberger,Matthew Nava,Matthew Nava,David Patterson,David Patterson,John F. Stanton,G. Barney Ellison,Michael C. McCarthy +12 more
TL;DR: The structure cis-1,3-butadiene is unambiguously confirmed experimentally to indeed be gauche with a substantial dihedral angle of 34°, in excellent agreement with theory.
Journal ArticleDOI
Spectroscopic characterization of isomerization transition states.
Joshua H. Baraban,P. Bryan Changala,Georg Ch. Mellau,John F. Stanton,Anthony J. Merer,Anthony J. Merer,Robert W. Field +6 more
TL;DR: A method for extracting transition state energies and properties from a characteristic pattern found in frequency-domain spectra of isomerizing systems, which can be understood using the concept of effective frequency.
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Discovery of a Missing Link: Detection and Structure of the Elusive Disilicon Carbide Cluster.
Michael C. McCarthy,Joshua H. Baraban,P. Bryan Changala,John F. Stanton,Marie-Aline Martin-Drumel,Sven Thorwirth,Carl A. Gottlieb,Neil J. Reilly +7 more
TL;DR: Now that all four Si(m)C(n) clusters with m + n = 3 have been observed experimentally, their structure and chemical bonding can be rigorously compared and Si2C is an extremely promising candidate for detection with radio telescopes.
Journal ArticleDOI
High-accuracy estimates for the vinylidene-acetylene isomerization energy and the ground state rotational constants of :C═CH2.
TL;DR: The thermochemical calculations presented here also allow a determination of the H2CC-H bond energy of the vinyl radical at the HEAT-345(Q) level of theory, which is 77.7 ± 0.3 kcal mol(-1).