K
Kevin Deplanche
Researcher at University of Birmingham
Publications - 28
Citations - 1344
Kevin Deplanche is an academic researcher from University of Birmingham. The author has contributed to research in topics: Catalysis & Palladium. The author has an hindex of 20, co-authored 28 publications receiving 1194 citations.
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Journal ArticleDOI
Involvement of hydrogenases in the formation of highly catalytic Pd(0) nanoparticles by bioreduction of Pd(II) using Escherichia coli mutant strains.
TL;DR: Electron microscopy suggested that the location of the resulting Pd(0) deposits was as expected from the subcellular localization of the particular hydrogenase involved in the reduction process, and Membrane separation experiments established that PD(II) reductase activity is membrane-bound and that hydrogenases are required to initiate Pd (II) reduction.
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Biorecovery of gold by Escherichia coli and Desulfovibrio desulfuricans
TL;DR: Microbial precipitation of gold was achieved using Escherichia coli and Desulfovibrio desulfuricans provided with H2 as the electron donor and the concept was successfully applied to recover 100% of the gold from acidic leachate obtained from jewellery waste.
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Novel supported Pd hydrogenation bionanocatalyst for hybrid homogeneous/heterogeneous catalysis
N.J. Creamer,I.P. Mikheenko,Ping Yong,Kevin Deplanche,D. Sanyahumbi,Joseph Wood,Katrin Pollmann,Mohamed L. Merroun,Sonja Selenska-Pobell,Lynne E. Macaskie +9 more
TL;DR: In this paper, a biologically supported nano-Pd contains particles of size ∼5nm and below, as determined using magnetic measurements (SQUID) and EXAFS spectroscopy.
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Microbial synthesis of core/shell gold/palladium nanoparticles for applications in green chemistry
Kevin Deplanche,Mohamed L. Merroun,Merixtell Casadesus,Dung Trung Tran,I.P. Mikheenko,James A. Bennett,Ju Zhu,Ian P. Jones,Gary Anthony Attard,Joseph Wood,Sonja Selenska-Pobell,Lynne E. Macaskie +11 more
TL;DR: A novel biochemical method based on the sacrificial hydrogen strategy to synthesize bimetallic gold–palladium nanoparticles (NPs) with a core/shell configuration that showed comparable catalytic activity to chemical counterparts with respect to the oxidation of benzyl alcohol, in air, and at a low temperature (90°C).
Journal ArticleDOI
Catalytic activity of biomass-supported Pd nanoparticles: Influence of the biological component in catalytic efficacy and potential application in 'green' synthesis of fine chemicals and pharmaceuticals
Kevin Deplanche,James A. Bennett,I.P. Mikheenko,Jacob B. Omajali,A.s. Wells,R.e. Meadows,Joseph Wood,Lynne E. Macaskie +7 more
TL;DR: Five gram negative and two gram positive bacterial strains known for their heavy metal tolerance or ability to reduce metal ions were coated with Pd(0) nanoparticles (NPs) via reduction of soluble Pd (II) ions under H2 following an initial uptake of PdCl4 2without added electron donor (’biosorption’), where the gram negative strains had a 5-fold greater capacity for PD(II).