M
Marisa C. Kozlowski
Researcher at University of Pennsylvania
Publications - 254
Citations - 8912
Marisa C. Kozlowski is an academic researcher from University of Pennsylvania. The author has contributed to research in topics: Catalysis & Enantioselective synthesis. The author has an hindex of 44, co-authored 224 publications receiving 7547 citations. Previous affiliations of Marisa C. Kozlowski include Merck & Co. & University of Wisconsin-Madison.
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Journal ArticleDOI
Aerobic Copper-Catalyzed Organic Reactions
TL;DR: The chemistry of copper is extremely rich because it can easily access Cu0, CuI, CuII, and CuIII oxidation states allowing it to act through one-electron or two-Electron processes, which feature confer a remarkably broad range of activities allowing copper to catalyze the oxidation and oxidative union of many substrates.
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Total synthesis of chiral biaryl natural products by asymmetric biaryl coupling
TL;DR: This tutorial review highlights the use of catalytic asymmetric 2-naphthol couplings in total synthesis including nigerone, hypocrellin, calphostin D, phleichrome, and cercosporin.
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Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings
TL;DR: Investigation into the mechanistic details of the cross-coupling of sp3-hybridized organoboron reagents via photoredox/nickel dual catalysis reveals an unexpected manifold for stereoinduction involving dynamic kinetic resolution (DKR) of a Ni(III) intermediate wherein the stereodetermining step is reductive elimination.
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Enantioselective oxidative biaryl coupling reactions catalyzed by 1,5-diazadecalin metal complexes: efficient formation of chiral functionalized BINOL derivatives.
TL;DR: Chiral 1,5-diaza-cis-decalins have been examined as ligands in the enantioselective oxidative biaryl coupling of substituted 2-naphthol derivatives and the relationship between the substitution of the naphthalene starting materials and reactivity/selectivity is determined.
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Enantioselective oxidative biaryl coupling reactions catalyzed by 1,5-diazadecalin metal complexes.
TL;DR: Under the optimal conditions employing a 1,5-diaza-cis-decalin copper(I) iodide complex with oxygen as the oxidant, rapid and highly selective couplings could be achieved.