The ultrafast relaxation and recombination dynamics of photogenerated electrons and holes in epitaxial graphene are studied using optical-pump Terahertz-probe spectroscopy. The conductivity in graphene at Terahertz frequencies depends on the carrier concentration as well as the carrier distribution in energy. Time-resolved studies of the conductivity can therefore be used to probe the dynamics associated with carrier intraband relaxation and interband recombination. We report the electron-hole recombination times in epitaxial graphene for the first time. Our results show that carrier cooling occurs on sub-picosecond time scales and that interband recombination times are carrier density dependent.

Ultrafast Optical-Pump Terahertz-Probe Spectroscopy of the Carrier Relaxation and Recombination Dynamics in Epitaxial Graphene

Graphene plasmons have been found to be an exciting plasmonic platform, thanks to their high field confinement and low phase velocity, motivating contemporary research to revisit established concepts in light–matter interaction. In a conceptual breakthrough over 80 years old, Cerenkov showed how charged particles emit shockwaves of light when moving faster than the phase velocity of light in a medium. To modern eyes, the Cerenkov effect offers a direct and ultrafast energy conversion scheme from charge particles to photons. The requirement for relativistic particles, however, makes Cerenkov emission inaccessible to most nanoscale electronic and photonic devices. Here we show that graphene plasmons provide the means to overcome this limitation through their low phase velocity and high field confinement. The interaction between the charge carriers flowing inside graphene and the plasmons enables a highly efficient two-dimensional Cerenkov emission, giving a versatile, tunable and ultrafast conversion mechanism from electrical signal to plasmonic excitation.

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Efficient plasmonic emission by the quantum Čerenkov effect from hot carriers in graphene

Hybrid nanostructures composed of graphene or other two-dimensional (2D) nanomaterials and plasmonic metal components have been extensively studied. The unusual properties of 2D materials are associated with their atomically thin thickness and 2D morphology, and many impressive structures enable the metal nanomaterials to establish various interesting hybrid nanostructures with outstanding plasmonic properties. In addition, the hybrid nanostructures display unique optical characteristics that are derived from the close conjunction of plasmonic optical effects and the unique physicochemical properties of 2D materials. More importantly, the hybrid nanostructures show several plasmonic electrical effects including an improved photogeneration rate, efficient carrier transfer, and a plasmon-induced "hot carrier", playing a significant role in enhancing device performance. They have been widely studied for plasmon-enhanced optical signals, photocatalysis, photodetectors (PDs), and solar cells. In this review, the developments in the field of metal/2D hybrid nanostructures are comprehensively described. Preparation of hybrid nanostructures is first presented according to the 2D material type, as well as the metal nanomaterial morphology. The plasmonic properties and the enabled applications of the hybrid nanostructures are then described. Lastly, possible future research in this promising field is discussed.

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Hybrid nanostructures of metal/two-dimensional nanomaterials for plasmon-enhanced applications

DOI: 10.1002/adom.201801433 Scientific American selects plasmonic sensing as the top 10 emerging technologies of 2018.[15] Almost every single new plasmonic or photonic structure would be explored to test its sensing ability.[16–29] These works tend to report the sensing performance of their own structure. Some declare that their sensitivity breaks the world record. However, there is still a missing literature on what the world record really is, the gap between the experiments and the theoretical limit, as well as the differences between metal-based plasmonic sensors and dielectric-based photonic sensors. To push plasmonic and photonic sensors into industrial applications, an optical sensing technology map is absolutely necessary. This review aims to cover a wide range of most representative plasmonic and photonic sensors, and place them into a single map. The sensor performances of different structures will be distinctly illustrated. Future researchers could plot the sensing ability of their new sensors into this technology map and gauge their performances in this field. In this review, we focus on optical refractive index (RI) sensors with no fluorescent labeling required. We will utilize two parameters to characterize and compare the performance of optical RI sensors: sensitivity to RI change (denoted by symbol SRI) and figure of merit (in short, FoM). For simplicity, we restrict our discussions to bulk RI change, where the change in RI occurs within the whole sample. There is another case where the RI variation occurs only within a very small volume close to the sensor surface. This surface RI sensitivity is proportional to the bulk RI sensitivity, the ratio of the thickness of the layer within which the surface RI variation occurs, and the penetration depth of the optical mode.[6] The bulk RI sensitivity defines the ratio of the change in sensor output (e.g., resonance angle, intensity, or resonant wavelength) to the bulk RI variations. Here, we limit our discussions to the spectral interrogations and the bulk RI sensitivity SRI is given by[3,5–7,30]

Optical Refractive Index Sensors with Plasmonic and Photonic Structures: Promising and Inconvenient Truth

In this review, we survey the recent advances in nonlinear optics and the applications of two-dimensional (2D) materials. We briefly cover the key developments pertaining to research in the nonlinear optics of graphene, the quintessential 2D material. Subsequently, we discuss the linear and nonlinear optical properties of several other 2D layered materials, including transition metal chalcogenides, black phosphorus, hexagonal boron nitride, perovskites, and topological insulators, as well as the recent progress in hybrid nanostructures containing 2D materials, such as composites with dyes, plasmonic particles, 2D crystals, and silicon integrated structures. Finally, we highlight a few representative current applications of 2D materials to photonic and optoelectronic devices.

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Nonlinear optical properties and applications of 2D materials: theoretical and experimental aspects

A physical phenomenon has been found: in a structure of nanometal film with dielectric-medium loading, the surface polaritons excited by a uniformly moving electron bunch can be transformed into Cherenkov radiation with intensity enhancement in the medium. Based on this mechanism, the surface polariton Cherenkov light radiation source is presented and explored in the Letter. The results show that surface polariton Cherenkov light radiation source can generate radiation, from visible light to the ultraviolet frequency regime and the radiation power density can reach or even exceed 10(8) W/cm(2) depending on the beam energy and current density. It is a tunable and miniature light radiation source promising to be integrated on a chip and built into a light radiation source array.

Surface Polariton Cherenkov Light Radiation Source

Although surface plasmon polaritons (SPPs) resonance in graphene can be tuned in the terahertz regime, transforming such SPPs into coherent terahertz radiation has not been achieved. Here, we propose a graphene-based coherent terahertz radiation source with greatly enhanced intensity. The radiation works at room temperature, it is tunable and can cover the whole terahertz regime. The radiation intensity generated with this method is 400 times stronger than that from SPPs at a conventional dielectric or semiconducting surface and is comparable to that from the most advanced photonics source such as a quantum cascade laser. The physical mechanism for this strong radiation is presented. The phase diagrams defining the parameters range for the occurrence of radiation is also shown.

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Coherent and tunable terahertz radiation from graphene surface plasmon polaritons excited by an electron beam

We demonstrate a mechanism of efficiently transforming surface plasmon polaritons (SPPs) into Cherenkov terahertz (THz) radiation. In a structure where multilayer graphene is deposited on a dielectric substrate with a buffer layer, the energy of the SPPs can be significantly enhanced. The dispersion of SPPs crosses the light line of the substrate if the buffer layer has a low permittivity relative to the substrate. As a result, the SPPs can be readily transformed into radiation without the need of wavevector compensation. Compared to the radiation from structures without graphene, the radiation power density is enhanced by nearly three orders of magnitude due to the field enhancement of SPPs. Our results could provide a promising way for developing room temperature, tunable, coherent, and intense THz radiation sources to cover the entire THz regime.

Cherenkov terahertz radiation from graphene surface plasmon polaritons excited by an electron beam

This paper explores the physics of the electromagnetic diffraction radiation of a subwavelength holes array excited by a set of evanescent waves generated by a line charge of electron beam moving parallel to the array. Activated by a uniformly moving line charge, numerous physical phenomena occur such as the diffraction radiation on both sides of the array as well as the electromagnetic penetration or transmission below or above the cut-off through the holes. As a result the subwavelength holes array becomes a radiation array. Making use of the integral equation with relevant Green's functions, an analytical theory for such a radiation system is built up. The results of the numerical calculations based on the theory agree well with that obtained by the computer simulation. The relation among the effective surface plasmon wave, the electromagnetic penetration or transmission of the holes and the diffraction radiation is revealed. The energy dependence of and the influence of the hole thickness on the diffraction radiation and the electromagnetic penetration or transmission are investigated in detail. Therefore, a distinct diffraction radiation phenomenon is discovered.

Electromagnetic diffraction radiation of a subwavelength-hole array excited by an electron beam.

We demonstrate optical bistability in a prism-air-graphene-dielectric structure. Under a moderate electric field in the terahertz frequency regime, the third order nonlinear optical conductivity is comparable to the linear conductivity. The nonlinear conductivity enhances the energy of surface plasmon polaritons. Both the energy and frequency of the surface plasmon polaritons depend on the strength of the nonlinear current in the graphene layer. When considering excitation in the Kretschmann configuration, the reflectance as a function of frequency exhibits bistability. The origin of the bistability is the field dependence of the plasmon mode. We have determined the parameter regime for the occurrence of bistability in this structure.

/pdf/optical-bistability-induced-by-nonlinear-surface-plasmon-4ccnitve9w.pdf

Min Hu

Papers

Surface Polariton Cherenkov Light Radiation Source

Coherent and tunable terahertz radiation from graphene surface plasmon polaritons excited by an electron beam

Cherenkov terahertz radiation from graphene surface plasmon polaritons excited by an electron beam

Electromagnetic diffraction radiation of a subwavelength-hole array excited by an electron beam.

Optical bistability induced by nonlinear surface plasmon polaritons in graphene in terahertz regime