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Nikita V. Muravyev

Researcher at Russian Academy of Sciences

Publications -  71
Citations -  1381

Nikita V. Muravyev is an academic researcher from Russian Academy of Sciences. The author has contributed to research in topics: Thermal decomposition & Chemistry. The author has an hindex of 15, co-authored 53 publications receiving 679 citations. Previous affiliations of Nikita V. Muravyev include Semenov Institute of Chemical Physics & A. N. Nesmeyanov Institute of Organoelement Compounds.

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Pursuing reliable thermal analysis techniques for energetic materials: decomposition kinetics and thermal stability of dihydroxylammonium 5,5′-bistetrazole-1,1′-diolate (TKX-50)

TL;DR: This study revealed that none of the Arrhenius parameters reported before can properly describe the complex two-stage decomposition process of TKX-50, and showed the superior performance of the isoconversional methods combined with isothermal measurements, which yielded the most reliable kinetic parameters of TkX- 50 thermolysis.
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Pyrazole-Tetrazole Hybrid with Trinitromethyl, Fluorodinitromethyl, or (Difluoroamino)dinitromethyl Groups: High-Performance Energetic Materials.

TL;DR: Density, oxygen balance, and enthalpy of formation are enhanced by the presence of these oxygen-containing units, and it is proposed to use new criterion, ΔOED, that can serve as a measure of the tightness of molecular packing upon crystal formation.
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Critical Appraisal of Kinetic Calculation Methods Applied to Overlapping Multistep Reactions.

TL;DR: The model-fitting approach using simultaneously TG and DSC data was found to be the most useful for the complex processes assumed in the study, and mathematical and kinetic deconvolution approaches and formal kinetic description were highlighted.
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Kinetic analysis of overlapping multistep thermal decomposition comprising exothermic and endothermic processes: thermolysis of ammonium dinitramide

TL;DR: The thermal decomposition of ADN was successfully modeled as partially overlapping exothermic and endothermic reaction steps using kinetic deconvolution analysis to demonstrate the validity of the methodology and its applicability to similar complex reaction processes.