O
Olivier Baudoin
Researcher at University of Basel
Publications - 152
Citations - 7096
Olivier Baudoin is an academic researcher from University of Basel. The author has contributed to research in topics: Catalysis & Palladium. The author has an hindex of 39, co-authored 147 publications receiving 6231 citations. Previous affiliations of Olivier Baudoin include University of California, San Diego & University of Lyon.
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Journal ArticleDOI
Divergent Synthesis of Aeruginosins Based on a C(sp3)H Activation Strategy
TL;DR: A general and scalable access to the aeruginosin family of marine natural products, exhibiting potent inhibitory activity against serine proteases, is reported, enabled by the strategic use of two recently implemented Pd-catalyzed C(sp(3))-H activation reactions.
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Efficient and Divergent Total Synthesis of (-)-Epicoccin G and (-)-Rostratin A Enabled by Double C(sp3)-H Activation.
Pierre Thesmar,Olivier Baudoin +1 more
TL;DR: This study reports the enantioselective, scalable and diver-gent total synthesis of two symmetrical pentacyclic dithiodiketopiperazines, (-)-epicoccin G and (-)-rostratin A, obtained for the first time on a 500 mg scale through the optimization of each step and valida-tion on multigram quantities.
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Intramolecular PdII-catalyzed dehydrogenative C(sp3)–C(sp2) coupling: an alternative to Pd0-catalyzed C(sp3)–H arylation from aryl halides?
Cathleen Pierre,Olivier Baudoin +1 more
TL;DR: This reaction shows interesting chemo- and diastereoselectivity, however a direct comparison showed that it is yet much less efficient than the two-step sequence composed of electrophilic halogenation and Pd 0 -catalyzed C(sp 3 )–H arylation.
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Stabilization of DNA Triple Helices by Crescent‐Shaped Dibenzophenanthrolines
Olivier Baudoin,Christophe Marchand,Marie-Paule Teulade-Fichou,Jean-Pierre Vigneron,Jian-Sheng Sun,Thérèse Garestier,Claude Hélène,Jean-Marie Lehn +7 more
TL;DR: New aminoalkyl dibenzophenanthrolines, which have a large angular aromatic structure, are efficient triplex-stabilizing ligands for this purpose of improving the stability of DNA triple helices.
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Copper‐Catalyzed Trifluoromethylation of Aliphatic N‐Arylhydrazones: A Concise Synthetic Entry to 2‐Trifluoromethylindoles from Simple Aldehydes
TL;DR: In this article, the trifluoromethylation of N,N-disubstituted hydrazones using the Togni reagent is demonstrated to proceed efficiently for aliphatic aldehyde-derived substrates.