Omar M. Yaghi

TL;DR: In this article, a process for preparing an organometallic framework material comprising reacting at least one metal salt with at least at least bidentate compound capable of coordination to the metal ion of said metal salt, in the presence of an aqueous solvent system and at least base wherein at least the bidentates comprises at least carboxy group and a further group which is not a carboxyspecific group and which is capable of forming a hydrogen bridge linkage.

TL;DR: The tetrahedral cluster Ge4S10 4- and the rodlike ligand 4,4′-bipyridine are utilized in addition copolymerization reactions with the metal (II) ions of Mn, Fe, Co, Cu, and Zn in the preparation of 3-D open-framework solids.

TL;DR: What defines a sequence-dependent material, and how the concept can be realized in crystals of extended structures such as metal-organic frameworks are discussed.

TL;DR: In this article , the first covalent incorporation of reactive aliphatic amine species into COFs was reported through the crystallization of an imine-linked COF, termed COF-609-Im, followed by conversion of its imine linkage to base-stable tetrahydroquinoline linkage through aza-Diels-Alder cycloaddition.

TL;DR: In this article, the pore environments of a series of isoreticular metal-organic frameworks (IRMOF) have been studied using hyperpolarized (HP) 129Xe NMR spectroscopy.