R
Rafael Ruiz-García
Researcher at University of Valencia
Publications - 69
Citations - 3551
Rafael Ruiz-García is an academic researcher from University of Valencia. The author has contributed to research in topics: Magnetic susceptibility & Molecule. The author has an hindex of 30, co-authored 65 publications receiving 3224 citations. Previous affiliations of Rafael Ruiz-García include Pierre-and-Marie-Curie University & Catalan Institution for Research and Advanced Studies.
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Journal ArticleDOI
Magnetic properties of six-coordinated high-spin cobalt(II) complexes: Theoretical background and its application
Francesc Lloret,Miguel Julve,Joan Cano,Joan Cano,Rafael Ruiz-García,Rafael Ruiz-García,Emilio Pardo +6 more
TL;DR: In this paper, an empirical expression to fit the magnetic susceptibility of polycrystalline samples of mononuclear Co(II) complexes with an axial distortion, the variable parameters being Δ (axial distortion), α (orbital reduction factor), and λ (spin-orbit coupling), was proposed.
Journal ArticleDOI
Field-Induced Slow Magnetic Relaxation in a Six-Coordinate Mononuclear Cobalt(II) Complex with a Positive Anisotropy
Julia Vallejo,Isabel Castro,Rafael Ruiz-García,Joan Cano,Miguel Julve,Francesc Lloret,Giovanni De Munno,Wolfgang Wernsdorfer,Emilio Pardo +8 more
TL;DR: Slow magnetic relaxation effects were observed for 1 in the presence of a dc magnetic field, constituting the first example of field-induced single-molecule magnet behavior in a mononuclear six-coordinate Co(II) complex with a transverse anisotropy energy barrier.
Journal ArticleDOI
Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆
Jesús Ferrando-Soria,Julia Vallejo,María Castellano,José Martínez-Lillo,Emilio Pardo,Joan Cano,Isabel Castro,Francesc Lloret,Rafael Ruiz-García,Miguel Julve +9 more
TL;DR: Molecular magnetism has travelled a long way from the pioneering studies on electron exchange and double exchange or spin crossover and valence tautomerism in small oligonuclear complexes, from mono-to di-and tetranuclear species, to the current investigations about magnetic anisotropy and spin dynamics or quantum coherence of simple mono- or large polynuclear complexes.
Journal ArticleDOI
Ligand design for multidimensional magnetic materials: a metallosupramolecular perspective.
Emilio Pardo,Rafael Ruiz-García,Joan Cano,Joan Cano,Xavier Ottenwaelder,Rodrigue Lescouëzec,Yves Journaux,Francesc Lloret,Miguel Julve +8 more
TL;DR: The aim and scope of this review is to show the general validity of the 'complex-as-ligand' approach for the rational design of metallosupramolecular assemblies of increasing structural and magnetic complexity.
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Supramolecular coordination chemistry of aromatic polyoxalamide ligands: A metallosupramolecular approach toward functional magnetic materials
Marie-Claire Dul,Emilio Pardo,Rodrigue Lescouëzec,Yves Journaux,Jesús Ferrando-Soria,Rafael Ruiz-García,Joan Cano,Miguel Julve,Francesc Lloret,Danielle Cangussu,Cynthia L. M. Pereira,Humberto O. Stumpf,Jorge Pasán,Catalina Ruiz-Pérez +13 more
TL;DR: In this article, a family of aromatic polyoxalamide (APOXA) ligands with first-row transition metal ions has been used for the design of metallosupramolecular assemblies.