Polymers from triglyceride oils

Vegetable oil-based polymeric materials: synthesis, properties, and applications

Veggie-based products: Vegetable-oil-based polymeric materials, prepared by free radical, cationic, and olefin metathesis polymerizations, range from soft rubbers to ductile or rigid plastics, and to high-performance biocomposites and nanocomposites. They display a wide range of thermophysical and mechanical properties and may find promising applications as alternatives to petroleum-based polymers.

Vegetable oils are considered to be among the most promising renewable raw materials for polymers, because of their ready availability, inherent biodegradability, and their many versatile applications. Research on and development of vegetable oil based polymeric materials, including thermosetting resins, biocomposites, and nanocomposites, have attracted increasing attention in recent years. This Minireview focuses on the latest developments in the preparation, properties, and applications of vegetable oil based polymeric materials obtained by free radical, cationic, and olefin metathesis polymerizations. The novel vegetable oil based polymeric materials obtained range from soft rubbery materials to ductile or rigid plastics and to high-performance biocomposites and nanocomposites. These vegetable oil based polymeric materials display a wide range of thermophysical and mechanical properties and should find useful applications as alternatives to their petroleum-based counterparts.

Novel polymeric materials from vegetable oils and vinyl monomers: preparation, properties, and applications.

Experimental studies of spontaneous combustion and anaerobic cooling of coal

Green composite films prepared from cellulose, starch and lignin in room-temperature ionic liquid

Low-temperature oxidation of some Turkish coals

Syntheses of wholly natural polymeric linseed oil (PLO) containing peroxide groups have been reported. Peroxidation, epoxidation and/or perepoxidation reactions of linseed oil, either under air or under oxygen flow at room temperature, resulted in polymeric peroxides, PLO-air and PLO-ofl, containing 1.3 and 3.5 wt.-% of peroxide, with molecular weights of 2 100 and 3 780 Da, respectively. PLO-air contained cross-linked film up to 46.1 wt.-% after a reaction time of 60 d, associated with a waxy, soluble part (PLO-air-s) that was isolated with chloroform extraction. PLO-ofl was obtained as a waxy, viscous liquid without any cross-linked part at the end of 24 d under visible irradiation and oxygen flow. Polymeric peroxides, PLO-air-s and PLO-ofl initiated the free radical polymerization of both methyl methacrylate (MMA) and styrene (S) to give PMMA-graft-PLO and PS-graft-PLO graft copolymers in high yields with Mw varying from 37 to 470 kDa. The polymers obtained were characterized by FT-IR, (1)H NMR, TGA, DSC and GPC techniques. Cross-linked polymers were also studied by means of swelling measurements. PMMA-graft-PLO graft copolymer film samples were also used in cell-culture studies. Fibroblast cells were well adhered and proliferated on the copolymer film surfaces, which is important in tissue engineering.

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Synthesis and characterization of polymeric linseed oil grafted methyl methacrylate or styrene

Characterization and non-isothermal decomposition kinetics of some Turkish bituminous coals by thermal analysis

By-product generation from coal combustion in coal-fired thermal power plants has been increasing worldwide and reached to 125 million tons in the U.S. and 100 million tons in Europe. Coal-fired thermal power plants have a share of about 20% in Turkey's electricity production. Almost 57 million tons of coal with varying ash content of 20–55% was consumed in those plants. Uranium and thorium radioactivity of ashes of low rank coals limits the use of ashes. Consuming local bituminous coals, Catalagzi Thermal Power Station has been producing 0.65 million tons of ash including fly ash (80%) and bottom ash (20%), which have a potential use in civil engineering. The majority of the fly ash has already been used in cement or directly in concrete mortars. This study was aimed to evaluate the bottom ash of the CATES. For this purpose, bottom ash was ground in a pilot scale set including a vertical stirring mill. The set had the controlled feeding, separation, and collection facilities to represent industr...

Sait Kizgut

Papers

Low-temperature oxidation of some Turkish coals

Synthesis and characterization of polymeric linseed oil grafted methyl methacrylate or styrene

Characterization and non-isothermal decomposition kinetics of some Turkish bituminous coals by thermal analysis

Stirred Grinding of Coal Bottom Ash to Be Evaluated as a Cement Additive

Open and closed circuit dry grinding of cement mill rejects in a pilot scale vertical stirred mill