S
Sébastien Floquet
Researcher at Université Paris-Saclay
Publications - 53
Citations - 986
Sébastien Floquet is an academic researcher from Université Paris-Saclay. The author has contributed to research in topics: Polyoxometalate & Chemistry. The author has an hindex of 16, co-authored 44 publications receiving 770 citations. Previous affiliations of Sébastien Floquet include Centre national de la recherche scientifique.
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Journal ArticleDOI
Polyoxometalate, Cationic Cluster, and γ-Cyclodextrin: From Primary Interactions to Supramolecular Hybrid Materials
Mhamad Aly Moussawi,Nathalie Leclerc-Laronze,Sébastien Floquet,Pavel A. Abramov,Maxim N. Sokolov,Stéphane Cordier,Anne Ponchel,Eric Monflier,Hervé Bricout,David Landy,Mohamed Haouas,Jérôme Marrot,Emmanuel Cadot +12 more
TL;DR: A three-component supramolecular hybrid system built from specific recognition processes involving a Dawson-type polyoxometalate (POM), [P2W18O62]6-, a cationic electron-rich cluster [Ta6Br12(H2O)6]2+, and γ-cyclodextrin (γ-CD) is reported on.
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A building block strategy to access sulfur-functionalized polyoxometalate based systems using {Mo2S2O2} and {Mo3S4} as constitutional units, linkers or templates.
Emmanuel Cadot,Maxim N. Sokolov,Vladimir P. Fedin,Corine Simonnet-Jégat,Sébastien Floquet,Francis Sécheresse +5 more
TL;DR: Specific reaction parameters and considerations will be pointed out showing that a deliberate pure inorganic supramolecular chemistry based on weak interactions, flexibility and dynamic is possible with polyoxometalates.
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Nonconventional Three-Component Hierarchical Host-Guest Assembly Based on Mo-Blue Ring-Shaped Giant Anion, γ-Cyclodextrin, and Dawson-type Polyoxometalate.
Mhamad Aly Moussawi,Mohamed Haouas,Sébastien Floquet,William Shepard,Pavel A. Abramov,Maxim N. Sokolov,Vladimir P. Fedin,Stéphane Cordier,Anne Ponchel,Eric Monflier,Jérôme Marrot,Emmanuel Cadot +11 more
TL;DR: The formation of this three-component hybrid assembly from one-pot procedure, in water and using nearly stoichiometric conditions, is discussed in terms of the driving forces orchestrating this highly efficient multilevel recognition process.
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Probing Dynamic Library of Metal-Oxo Building Blocks with γ-Cyclodextrin
Clément Falaise,Mhamad Aly Moussawi,Sébastien Floquet,Pavel A. Abramov,Maxim N. Sokolov,Mohamed Haouas,Emmanuel Cadot +6 more
TL;DR: The host-guest stabilization of the M6O192- species with M = Mo or W from aqueous solution using γ-cyclodextrin as trapping agent reveals remarkable hydrolytic stability that offers new opportunities for exploring potentialities of molybdates or tungstates in the field of biology and medicine, when combined to CDs as efficient drug carrier/delivery agents.
Journal ArticleDOI
Polyoxometalates paneling through {Mo2O2S2} coordination: cation-directed conformations and chemistry of a supramolecular hexameric scaffold.
Jerome Marrot,Marie Anne Pilette,Mohamed Haouas,Sébastien Floquet,Francis Taulelle,Xavier López,Josep M. Poblet,Emmanuel Cadot +7 more
TL;DR: Density functional methodology (DFT) has been applied to compute the geometries and energies of dimer (3), tetramer (2), and hexamer (1) based on {AsW(9)O(33)} (POM) and {Mo(2)O (2)S(2)} (L) units.