C
Corine Simonnet-Jégat
Researcher at Université Paris-Saclay
Publications - 41
Citations - 650
Corine Simonnet-Jégat is an academic researcher from Université Paris-Saclay. The author has contributed to research in topics: Polyoxometalate & Photopolymer. The author has an hindex of 14, co-authored 41 publications receiving 492 citations. Previous affiliations of Corine Simonnet-Jégat include Centre national de la recherche scientifique & Pierre-and-Marie-Curie University.
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Journal ArticleDOI
A building block strategy to access sulfur-functionalized polyoxometalate based systems using {Mo2S2O2} and {Mo3S4} as constitutional units, linkers or templates.
Emmanuel Cadot,Maxim N. Sokolov,Vladimir P. Fedin,Corine Simonnet-Jégat,Sébastien Floquet,Francis Sécheresse +5 more
TL;DR: Specific reaction parameters and considerations will be pointed out showing that a deliberate pure inorganic supramolecular chemistry based on weak interactions, flexibility and dynamic is possible with polyoxometalates.
Journal ArticleDOI
A new strontium bromide MOF composite with improved performance for solar energy storage application
Pierre D'Ans,Pierre D'Ans,Emilie Courbon,Anastasia Permyakova,Farid Nouar,Corine Simonnet-Jégat,Flavien Bourdreux,Loïc Malet,Christian Serre,Marc Frère,Nathalie Steunou +10 more
TL;DR: Using strontium bromide encapsulated in the mesoporous MIL-101(Cr) Metal-Organic Framework, a heat storage density of 233kW/h/m³ could be achieved, by using water vapor at a partial pressure as low as 1.25kPa as mentioned in this paper.
Journal ArticleDOI
Capture of the [Mo3S4]4+ Cluster within a {Mo18} Macrocycle Yielding a Supramolecular Assembly Stabilized by a Dynamic H-Bond Network
Sylvain Duval,Sébastien Floquet,Corine Simonnet-Jégat,Jérôme Marrot,Rosa Ngo Biboum,Bineta Keita,Louis Nadjo,Mohamed Haouas,Francis Taulelle,Emmanuel Cadot +9 more
TL;DR: The dinuclear individual species in solution gave rise to cis-trans equilibrium, while in the presence of the oxothiomolybdenum ring 1a, the dinuclear unit is maintained as a frozen cis complex and DOSY NMR provides a definitive argument for the integrity of the supramolecular assembly.
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Selective Inclusion of Cu+ and Ag+ Electron‐Rich Metallic Cations within Supramolecular Polyoxometalates Based on {AsW9O33}{Mo3S4} Combinations
Sylvain Duval,Marie-Anne Pilette,Jerome Marrot,Corine Simonnet-Jégat,Maxim N. Sokolov,Emmanuel Cadot +5 more
TL;DR: UV/Vis studies in solution indicate that the stability of the dimeric assemblies of 2, 3 and 4 is significantly enhanced by the presence of Cu(+) or Ag(+) ions, which act as additional coordination linkers within the supramolecular cluster.
Journal ArticleDOI
Single-Molecule Magnet Behavior of Individual Polyoxometalate Molecules Incorporated within Biopolymer or Metal–Organic Framework Matrices
William Salomon,Yanhua Lan,Eric Rivière,Shu Yang,Catherine Roch-Marchal,Anne Dolbecq,Corine Simonnet-Jégat,Nathalie Steunou,Nathalie Leclerc-Laronze,Laurent Ruhlmann,Talal Mallah,Wolfgang Wernsdorfer,Pierre Mialane +12 more
TL;DR: In Fe6 W18 @Gel, the SMM properties of the embedded molecules are close to those of the crystals, with clear quantum tunneling steps in the hysteresis loops, and magnetic studies indicate that the POMs are magnetically well isolated.