C
Clément Falaise
Researcher at Université Paris-Saclay
Publications - 58
Citations - 1563
Clément Falaise is an academic researcher from Université Paris-Saclay. The author has contributed to research in topics: Aqueous solution & Supramolecular chemistry. The author has an hindex of 21, co-authored 48 publications receiving 1110 citations. Previous affiliations of Clément Falaise include Oregon State University & Centre national de la recherche scientifique.
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Journal ArticleDOI
Capture of iodine in highly stable metal–organic frameworks: a systematic study
Clément Falaise,Christophe Volkringer,Jacques Facqueur,Till Bousquet,Laurent Gasnot,Thierry Loiseau +5 more
TL;DR: A series of aluminum-based metal-organic frameworks were investigated for sorption of iodine (I2) in cyclohexane and the best sorption uptake was obtained with solids decorated by electro-donor groups attached to the organic ligand or the inorganic sub-network.
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Thorium terephthalates coordination polymers synthesized in solvothermal DMF/H2O system.
TL;DR: The main similitude with the parent system dedicated to tetravalent uranium concerns the possibility to stabilize the An6O8(H2O)6 core by terephthalate linkers and to reproduce An(bdc)2(DMF)2 for both actinides U(4+) and Th(4+).
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Three-dimensional MOF-type architectures with tetravalent uranium hexanuclear motifs (U6O8).
Clément Falaise,Christophe Volkringer,Jean-François Vigier,Natacha Henry,Arnaud Beaurain,Thierry Loiseau +5 more
TL;DR: Four metal-organic frameworks (MOF) with tetravalent uranium have been solvothermally synthesized by treating UCl4 with rigid dicarboxylate linkers in N,N-dimethylfomamide (DMF), showing that the structures are quite unstable upon removal of the encapsulated DMF solvent.
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Isolation of the Large {Actinide}38 Poly-oxo Cluster with Uranium
Clément Falaise,Christophe Volkringer,Jean-François Vigier,Arnaud Beaurain,Pascal Roussel,Pierre Rabu,Thierry Loiseau +6 more
TL;DR: By controlling the water content, a new poly-oxo-metalate species containing 38 uranium centers has been solvothermally synthesized in the presence of benzoic acid in tetrahydrofuran (THF).
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Probing Dynamic Library of Metal-Oxo Building Blocks with γ-Cyclodextrin
Clément Falaise,Mhamad Aly Moussawi,Sébastien Floquet,Pavel A. Abramov,Maxim N. Sokolov,Mohamed Haouas,Emmanuel Cadot +6 more
TL;DR: The host-guest stabilization of the M6O192- species with M = Mo or W from aqueous solution using γ-cyclodextrin as trapping agent reveals remarkable hydrolytic stability that offers new opportunities for exploring potentialities of molybdates or tungstates in the field of biology and medicine, when combined to CDs as efficient drug carrier/delivery agents.