(b) Write out the equations for the time dependence of ρ11, ρ22, ρ12 and ρ21 assuming that a light field interaction V = -μ12Ee iωt + c.c. couples only levels |1> and |2>, and that the excited levels exhibit spontaneous decay. (8 marks) (c) Under steady-state conditions, find the ratio of populations in states |2> and |3>. (3 marks) (d) Find the slowly varying amplitude ̃ ρ 12 of the polarization ρ12 = ̃ ρ 12e iωt . (6 marks) (e) In the limiting case that no decay is possible from intermediate level |3>, what is the ground state population ρ11(∞)? (2 marks) 2. (15 marks total) In a 2-level atom system subjected to a strong field, dressed states are created in the form |D1(n)> = sin θ |1,n> + cos θ |2,n-1> |D2(n)> = cos θ |1,n> sin θ |2,n-1>

The Quantum Theory of Light

It is shown that the ordinary semiclassical theory of the absorption of light by exciton states is not completely satisfactory (in contrast to the case of absorption due to interband transitions). A more complete theory is developed. It is shown that excitons are approximate bosons, and, in interaction with the electromagnetic field, the exciton field plays the role of the classical polarization field. The eigenstates of the system of crystal and radiation field are mixtures of photons and excitons. The ordinary one-quantum optical lifetime of an excitation is infinite. Absorption occurs only when "three-body" processes are introduced. The theory includes "local field" effects, leading to the Lorentz local field correction when it is applicable. A Smakula equation for the oscillator strength in terms of the integrated absorption constant is derived.

a Quantum-Mechanical Theory of the Contribution of Excitons to the Complex Dielectric Constant of Crystals.

Wave propagation and group velocity

We review some basic techniques for laser-induced adiabatic population transfer between discrete quantum states in atoms and molecules.

Laser-induced population transfer by adiabatic passage techniques.

心臓病診療プラクティス 16. 心不全を癒す

In traditional schemes of multilevel multilaser excitation, each laser pulse interacts with only one pair of states, and the rotating wave approximation (RWA) is applicable. Here we study the population transfer process in a three-state system when each of the two lasers interacts with each of the pair of states and when the Rabi frequencies characterizing the interaction strengths of the system are comparable to or larger than the difference of the transition frequencies. We show that complete and robust population transfer is possible under conditions more general than those hitherto considered necessary for stimulated Raman adiabatic passage (STIRAP) or for successive π pulses. Using adiabatic Floquet theory we show that successful population transfer can be interpreted as adiabatic passage by means of a transfer state which connects the initial and final states. The Floquet picture offers a convenient interpretation of the population transfer as accompanied by multiple absorption of photons from or emission into the laser fields.

Efficient population transfer by delayed pulses despite coupling ambiguity

We propose an implementation of the quantum search algorithm of a marked item in an unsorted list of N items by adiabatic passage in a cavity-laser-atom system. We use an ensemble of N identical three-level atoms trapped in a single-mode cavity and driven by two lasers. In each atom, the same level represents a database entry. One of the atoms is marked by having an energy gap between its two ground states. Appropriate time delays between the two laser pulses allow one to populate the marked state starting from an initial entangled state within a decoherence-free adiabatic subspace. The time to achieve such a process is shown to exhibit the {radical}(N) Grover speedup.

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Adiabatic quantum search scheme with atoms in a cavity driven by lasers

We show that rovibrational state selectivity can be achieved by chirped adiabatic passage of molecules that are adiabatically aligned by a nonresonant laser field. We develop the tools to design the appropriate frequency and amplitude modulations that allow us to select a given route in the Hilbert space that leads to a final complete excitation of the chosen state, by infrared or by Raman processes. This method allows us to select a given vibrational state in a well-defined rotational $J$ state.

State-selective chirped adiabatic passage on dynamically laser-aligned molecules

A quantum dynamics study of the benzopyran ring opening guided by laser pulses

We construct mode-selective effective models describing the interaction of N quantum emitters (QEs) with the localised surface plasmon polaritons (LSPs) supported by a spherical metal nanoparticle (MNP) in an arbitrary geometric arrangement of the QEs. We develop a general formulation in which the field response in the presence of the nanosystem can be decomposed into orthogonal modes with the spherical symmetry as an example. We apply the model in the context of quantum information, investigating on the possibility of using the LSPs as mediators of an efficient control of population transfer between two QEs. We show that a Stimulated Raman Adiabatic Passage configuration allows such a transfer via a decoherence-free dark state when the QEs are located on the same side of the MNP and very closed to it, whereas the transfer is blocked when the emitters are positioned at the opposite sides of the MNP. We explain this blockade by the destructive superposition of all the interacting plasmonic modes.

Stéphane Guérin

Papers

Efficient population transfer by delayed pulses despite coupling ambiguity

Adiabatic quantum search scheme with atoms in a cavity driven by lasers

State-selective chirped adiabatic passage on dynamically laser-aligned molecules

A quantum dynamics study of the benzopyran ring opening guided by laser pulses

Quantum Plasmonics with multi-emitters: Application to adiabatic control