Measurements of two-photon fluorescence excitation (TPE) spectra are presented for 11 common molecular fluorophores in the excitation wavelength range 690 nm < λ < 1050 nm. Results of excitation by ∼100-fs pulses of a mode-locked Ti:sapphire laser are corroborated by single-mode cw Ti:sapphire excitation data in the range 710 nm < λ < 840 nm. Absolute values of the TPE cross section for Rhodamine B and Fluorescein are obtained by comparison with one-photon-excited fluorescence, assuming equal emission quantum efficiencies. TPE action cross sections for the other nine fluorophores are also determined. No differences between one-photon- and two-photon-excited fluorescence emission spectra are found. TPE emission spectra are independent of excitation wavelength. With both pulsed and cw excitation the fluorescence emission intensities are strictly proportional to the square of the excitation intensity to within ±4% for excitation intensities sufficiently below excited-state saturation.

Measurement of two-photon excitation cross sections of molecular fluorophores with data from 690 to 1050 nm

4. Survey of Novel Multiphoton Active Materials 1257 4.1. Multiphoton Absorbing Systems 1257 4.2. Organic Molecules 1257 4.3. Organic Liquids and Liquid Crystals 1259 4.4. Conjugated Polymers 1259 4.4.1. Polydiacetylenes 1261 4.4.2. Polyphenylenevinylenes (PPVs) 1261 4.4.3. Polythiophenes 1263 4.4.4. Other Conjugated Polymers 1265 4.4.5. Dendrimers 1265 4.4.6. Hyperbranched Polymers 1267 4.5. Fullerenes 1267 4.6. Coordination and Organometallic Compounds 1271 4.6.1. Metal Dithiolenes 1271 4.6.2. Pyridine-Based Multidentate Ligands 1272 4.6.3. Other Transition-Metal Complexes 1273 4.6.4. Lanthanide Complexes 1275 4.6.5. Ferrocene Derivatives 1275 4.6.6. Alkynylruthenium Complexes 1279 4.6.7. Platinum Acetylides 1279 4.7. Porphyrins and Metallophophyrins 1279 4.8. Nanoparticles 1281 4.9. Biomolecules and Derivatives 1282 5. Nonlinear Optical Characterizations of Multiphoton Active Materials 1282

Multiphoton Absorbing Materials : Molecular Designs, Characterizations, and Applications

Graphene has been hailed as a wonderful material in electronics, and recently, it is the rising star in photonics, as well. The wonderful optical properties of graphene afford multiple functions of signal emitting, transmitting, modulating, and detection to be realized in one material. In this paper, the latest progress in graphene photonics, plasmonics, and broadband optoelectronic devices is reviewed. Particular emphasis is placed on the ability to integrate graphene photonics onto the silicon platform to afford broadband operation in light routing and amplification, which involves components like polarizer, modulator, and photodetector. Other functions like saturable absorber and optical limiter are also reviewed.

Graphene photonics, plasmonics, and broadband optoelectronic devices.

Two-photon absorption has important advantages over conventional one-photon absorption, which has led to applications in microscopy, microfabrication, three-dimensional data storage, optical power limiting, up-converted lasing, photodynamic therapy, and for the localized release of bio-active species. These applications have generated a demand for new dyes with high two-photon absorption cross-sections. This Review introduces the theory of two-photon absorption, surveys the wide range of potential applications, and highlights emerging structure-property correlations that can serve as guidelines for the development of efficient two-photon dyes.

Two-photon absorption and the design of two-photon dyes.

CRYSTALLINE MATERIALS Introduction Physical Properties Optical Properties Mechanical Properties Thermal Properties Magnetooptic Properties Electrooptic Properties Elastooptic Properties Nonlinear Optical Properties GLASSES Introduction Commercial Optical Glasses Specialty Optical Glasses Fused Silica Fluoride Glasses Chalcogenide Glasses Magnetooptic Properties Electrooptic Properties Elastooptic Properties Nonlinear Optical Properties Special Glasses POLYMERIC MATERIALS Optical Plastics Index of Refraction Nonlinear Optical Properties Thermal Properties Engineering Data METALS Physical Properties of Selected Metals Optical Properties Mechanical Properties Thermal Properties Mirror Substrate Materials LIQUIDS Introduction Water Physical Properties of Selected Liquids Index of Refraction Nonlinear Optical Properties Magnetooptic Properties Commercial Optical Liquids GASES Introduction Physical Properties of Selected Gases Index of Refraction Nonlinear Optical Properties Magnetooptic Properties Atomic Resonance Filters APPENDICES Safe Handling of Optical Materials Abbreviations, Acronyms, and Mineralogical or Common Names for Optical Materials Abbreviations for Methods of Preparing Optical Materials and Thin Films Fundamental Physical Constants Units and Conversion Factors

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Handbook of Optical Materials

Room temperature luminescence in CuI/AgI quantum dots

We report a sensitive single beam technique for measuring both the nonlinear refractive index and nonlinear absorption coefficient for a wide variety of materials. We describe the experiment and present a brief analysis including cases where nonlinear refraction is accompanied by nonlinear absorption. In these experiments the transmittance of a sample is measured through a finite aperture in the far-field as the sample is moved along the propagation path (z) of a focused Gaussian beam. The sign and magnitude of the nonlinear refraction are easily deduced from such a transmittance curve (Z-scan). Employing this technique a sensitivity of better than A/300 wavefront distortion has been achieved using picosecond frequency doubled N&YAG laser pulses. In cases where nonlinear refraction is accompanied by nonlinear absorption, it is possible to separately evaluate the nonlinear refraction as well as the nonlinear absorption by performing a second Z-scan with the aperture removed. We demonstrate this me...

Nonlinear optical characterization of organic materials

We present measurements of nonlinear absorption and refraction in semiconductors used in the realization of
optical limiters. We show that nonlinear refraction at 532 nm in ZnSe is caused by a negative third order
electronic Kerr effect in addition to the two-photon-absorption (2PA) induced carrier refraction. We have
used time-resolved beam distortion, picosecond time-resolved degenerate four-wave mixing and our
recently developed Z-scan technique to determine the sign and magnitude of the 2PA coefficient, the bound
electronic nonlinearity, n2 and the refractive index change per free carrier.

Nonlinearities in semiconductors for optical limiting

By chopping 820 nm 18 femtosecond (fs)-laser pulses, continuously generated by a self-mode locked Ti:Al2O3 laser at 82 MHz, into trains with both train-width and train-to-train separation considerably longer than the thermal diffusivity time constant τth of CS2, we conducted Z-scan measurements on it at various times relative to the leading pulse of each train (T's). As a result, we observed negative nonlinear refraction strengthening with T within τth and gradually stabilizing with T exceeding τth. We quantitatively explain the experimental results in terms of the thermal lensing effect. In particular, we attribute the heat generation to non-radiative relaxation of libration excited by individual 18 fs-pulses via stimulated Raman scattering. In contrast to the commonly held view of multi-photon excitation, we propose and verify a new heat-generating mechanism for the thermal lensing effect in CS2.

Thermal lensing effect of CS2 studied with femtosecond laser pulses.

Use was made of a novel Fabry–Perot interferometer technique to determine the variation of refractive index with temperature (∂n/∂T) of a potassium niobate crystal with a GaAlAs diode laser. The transverse intensity distributions of the laser transmitted through the crystal were found to be temperature dependent, and the ∂n/∂T values along crystallographic b and c axes were determined to be −4.5×10−5 and 6.1×10−5 °C−1, respectively. The temperature changes required for tangential tuning from transverse mode TEMqmn to TEMqm+1n and sagittal tuning from TEMqmn to TEMqmn+1 were found to be 0.29 and 1.27 °C, respectively, when the laser was polarized along the b axis. When the laser polarization was along the c axis, the tangential and sagittal tunings were found to be 0.10 and 0.54 °C, respectively. These differences between the tangential and sagittal directions indicated that the monolithic ring resonator used was indeed asymmetric.

Tai-Huei Wei

Papers

Room temperature luminescence in CuI/AgI quantum dots

Nonlinear optical characterization of organic materials

Nonlinearities in semiconductors for optical limiting

Thermal lensing effect of CS2 studied with femtosecond laser pulses.

Temperature variation of the refractive index of potassium niobate