Effects of various fillers on the sliding wear of polymer composites

In State of Art: Mechanical and tribological behaviour of polymeric composites based on natural fibres

Many different polymers and polymer composites are used for engineering applications in which friction and wear are critical issues. This article briefs (a) the importance of polymer tribology in general, (b) the special design principles of polymer composites for low friction and wear under sliding against smooth metallic counterparts, and (c) synergistic effects of nano-particles and traditional fillers and fibers for an optimal tribological performance. Based on these fundamental aspects, the article reviews traditional applications of polymeric tribo-components in mechanical and automotive engineering, including slide elements in textile machines, filament wound bushings for harsh environments, cages of high-precision ball bearings in dental turbines, and hybrid bushings in Diesel fuel injection pumps. A following chapter on special developments of tribo-components outlines (a) ways to achieve electrical conductivity of polymer bearings, (b) the enhancement of self-lubrication and self-healing potential by the incorporation of micro-capsules into the polymer matrix, (c) modern additive manufacturing methods for friction and wear loaded polymer parts, (d) the application and properties of high temperature polymer coatings, and (e) the composition and use of polymer composites under friction at cryogenic temperature conditions.

Polymer composites for tribological applications

Molybdenum disulfide (MoS2) is one of the most broadly utilized solid lubricants with a wide range of applications, including but not limited to those in the aerospace/space industry. Here we present a focused review of solid lubrication with MoS2 by highlighting its structure, synthesis, applications and the fundamental mechanisms underlying its lubricative properties, together with a discussion of their environmental and temperature dependence. The review also includes an extensive overview of the structure and tribological properties of doped MoS2, followed by a discussion of potential future research directions.

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Solid Lubrication with MoS2: A Review

This article is a state-of-the-art review of the use of cryogenic cooling using liquefied gases in machining. The review is classified into two major categories, namely cryogenic processing and cryogenic machining. In cryogenic processing also known as cryo-processing, the cutting tool material is subjected to cryogenic temperatures as a part of its heat treatment process. The majority of the reported studies identify that cryo-processing can considerably increase cutting tool life especially for high speed steel tools. It also identified that, in cryogenic machining, a cryogen is used as a cooling substance during cutting operations. The cryogen can be used to freeze the workpiece material and/or cutting tool. This article concludes that cryogenic cooling has demonstrated significant improvements in machinability by changing the material properties of the cutting tool and/or workpiece material at the cutting zone, altering the coefficient of friction and reducing the cutting temperature.

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State-of-the-art cryogenic machining and processing

Friction and wear of PTFE composites at cryogenic temperatures

Tribological behaviour of materials at cryogenic temperatures

Friction and wear of PEEK composites in vacuum environment

Tribological screening tests for the selection of raw materials for automotive brake pad formulations

MoS2 is a suitable solid lubricant for environments free of oxygen or water vapor (i.e. vacuum). Humid air degrades film properties due to oxidation accompanied by high wear and increasing coefficients of friction. The present study aims at the further development of sputtered pure MoS2 coatings, extending their applicability to varying environmental conditions by increasing the resistance against humidity. The systematic coating development process is supported by using an experimental Box–Behnken design with variations of the deposition parameters cathode voltage, target/substrate distance, temperature and argon gas pressure. In contrast to common one-factor-at-a-time (OFAT) studies, this approach enables a determination of interactions between deposition process parameters and tribological–mechanical MoS2 film properties. The tribological improvement focuses on a maximization of wear resistance in air and vacuum measured in ball-on-disk experiments. The evaluated mechanical properties are hardness, elastic modulus and residual stresses. These stresses were determined by the substrate curvature method. The study reveals that the residual stress state in the films and the hardness-to-modulus ratio are crucial for their tribological performance in humid air and vacuum environments. After a detailed determination of the relationships between deposition conditions and film properties, some selected microstructural analyses are presented which show that a substantially basal orientation of the lattice has positive effects on wear but also causes anisotropic film properties which result in fissile fracture of the coating if strong shock or point loads occur.

Thomas Gradt

Papers

Friction and wear of PTFE composites at cryogenic temperatures

Tribological behaviour of materials at cryogenic temperatures

Friction and wear of PEEK composites in vacuum environment

Tribological screening tests for the selection of raw materials for automotive brake pad formulations

Humidity resistant MoS2 coatings deposited by unbalanced magnetron sputtering