T
Tibor Szilvási
Researcher at University of Wisconsin-Madison
Publications - 126
Citations - 3231
Tibor Szilvási is an academic researcher from University of Wisconsin-Madison. The author has contributed to research in topics: Reactivity (chemistry) & Silylene. The author has an hindex of 28, co-authored 116 publications receiving 2476 citations. Previous affiliations of Tibor Szilvási include University of Alabama & Wisconsin Alumni Research Foundation.
Papers
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Journal ArticleDOI
Direct time-domain observation of attosecond final-state lifetimes in photoemission from solids
Zhensheng Tao,Cong Chen,Tibor Szilvási,Mark W. Keller,Manos Mavrikakis,Henry C. Kapteyn,Margaret M. Murnane +6 more
TL;DR: In this paper, the difference in lifetimes between photoelectrons born into free electron-like states and those excited into unoccupied excited states in the band structure of nickel was measured.
Journal Article
Direct time-domain observation of attosecond final-state lifetimes in photoemission from solids
Wenjing You,Zhensheng Tao,Cong Chen,Tibor Szilvási,Mark W. Keller,Manos Mavrikakis,Henry C. Kapteyn,Margaret M. Murnane +7 more
TL;DR: The application of attosecond pulse trains is reported to directly and unambiguously measure the difference in lifetimes between photoelectrons born into free electron–like states and those excited into unoccupied excited states in the band structure of nickel.
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A Bis(silylene)-Substituted ortho-Carborane as a Superior Ligand in the Nickel-Catalyzed Amination of Arenes
TL;DR: The synthesis and structure of the first 1,2-bis(NHSi)-substituted ortho-carborane (termed SiCCSi) is reported, and the strong donor character of the ligand enables [SiCCSi]NiBr2 to act as an outstanding precatalyst in the catalytic aminations of arenes, surpassing the activity of previously known molecular Ni-based precatalysts.
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A fragile zwitterionic phosphasilene as a transfer agent of the elusive parent phosphinidene (:PH).
TL;DR: In the presence of an N-heterocyclic carbene as an unsaturated organic substrate, the fragile phosphasilene 8 acts as a :PH transfer reagent, resulting in the formation of silylene 9 and phosphaalkene 11 bearing a terminal PH moiety.
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Can low-valent silicon compounds be better transition metal ligands than phosphines and NHCs?
Zsolt Benedek,Tibor Szilvási +1 more
TL;DR: In this paper, the potential application of experimentally characterized low-valent silicon compounds as transition metal ligands by computing the most important ligand properties, σ-donor and π-acceptor ability, ligand-to-metal charge transfer, and steric parameters and compared them to the generally used carbene and phosphine ligands.