We report a study of self-assembled beta-pleated sheets in B. mori silk fibroin films using thermal analysis and infrared spectroscopy. B. mori silk fibroin may stand as an exemplar of fibrous proteins containing crystalline beta-sheets. Materials were prepared from concentrated solutions (2−5 wt % fibroin in water) and then dried to achieve a less ordered state without beta-sheets. Crystallization of beta-pleated sheets was effected either by heating the films above the glass transition temperature (Tg) and holding isothermally or by exposure to methanol. The fractions of secondary structural components including random coils, alpha-helices, beta-pleated sheets, turns, and side chains were evaluated using Fourier self-deconvolution (FSD) of the infrared absorbance spectra. The silk fibroin films were studied thermally using temperature-modulated differential scanning calorimetry (TMDSC) to obtain the reversing heat capacity. The increment of the reversing heat capacity ΔCp0(Tg) at the glass transition fo...

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Determining Beta Sheet Crystallinity in Fibrous Proteins by Thermal Analysis and Infrared Spectroscopy

The functionalities of the untethered miniature swimming robots significantly decrease as the robot size becomes smaller, due to limitations of feasible miniaturized on-board components. Here we propose an untethered jellyfish-inspired soft millirobot that could realize multiple functionalities in moderate Reynolds number by producing diverse controlled fluidic flows around its body using its magnetic composite elastomer lappets, which are actuated by an external oscillating magnetic field. We particularly investigate the interaction between the robot's soft body and incurred fluidic flows due to the robot's body motion, and utilize such physical interaction to achieve different predation-inspired object manipulation tasks. The proposed lappet kinematics can inspire other existing jellyfish-like robots to achieve similar functionalities at the same length and time scale. Moreover, the robotic platform could be used to study the impacts of the morphology and kinematics changing in ephyra jellyfish.

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Multi-functional soft-bodied jellyfish-like swimming

Rapid industrialization has provided comforts to mankind but has also impacted the environment harmfully. There has been severe increase in the pollution due to several industries, in particular due to dye industry, which generate huge quantities of wastewater containing hazardous chemicals. Although tremendous developments have taken place for the treatment and management of such wastewater through chemical or biological processes, there is an emerging shift in the approach, with focus shifting on resource recovery from such wastewater and also their management in sustainable manner. This review article aims to present and discuss the most advanced and state-of-art technical and scientific developments about the treatment of dye industry wastewater, which include advanced oxidation process, membrane filtration technique, microbial technologies, bio-electrochemical degradation, photocatalytic degradation, etc. Among these technologies, microbial degradation seems highly promising for resource recovery and sustainability and has been discussed in detail as a promising approach. This paper also covers the challenges and future perspectives in this field.

https://www.tandfonline.com/doi/pdf/10.1080/21655979.2020.1863034

A critical review on advances in the practices and perspectives for the treatment of dye industry wastewater.

Freeze casting – A review of processing, microstructure and properties via the open data repository, FreezeCasting.net

Composites. Part A, Applied science and manufacturing

Inspired by natural creatures, soft robots possess the unique advantages of large actuation and excellent adaptability. Untethered designs of soft robots are drawing more attention to researchers, but current research is limited. Also, there is an increasing need to improve the performance of bio-mimetic robots. This work describes an untethered soft robotic jellyfish with high mobility that can mimic a natural jellyfish's performance. The electrode of the robotic jellyfish is made by sandwiching carbon grease between two layers of dielectric elastomer film. The frame of the material, where six plastic paddles are attached, is made from a silicone elastomer. The robotic jellyfish has a maximum recorded swim speed of up to 1 cm s -1 , with a peak thrust force of 0.000 12 N. A finite element simulation is developed to study the performance of the robotic jellyfish in a theoretical manner. By embedding a compact remote-controlled power source, the robotic jellyfish is made autonomous. In this case, the max peak speed is around 0.5 cm s -1 . Ultimately, the working principles of the bio-mimetic robotic jellyfish can be useful in field studies and to guide the design of soft robots and flexible devices.

https://iopscience.iop.org/article/10.1088/1361-665X/aaed4f/pdf

Untethered soft robotic jellyfish

In this paper, we develop the novel approach to design and fabricate dielectric elastomer (DE) actuator integrating with 3D printed flexible structures, demonstrating large deformation and multi-functionalities. This technique facilitates the combination of complex soft structures fused on the DE membrane without any extra adhesive. Based on the DE actuator, a soft gripper has been fabricated and characterized in terms of bending angle and blocked force. Finite element method (FEM) simulations precisely predict the electromechanical behaviors, guiding the design of the soft actuator. With optimal design, the finger-like soft actuator can generate large actuation with the bending angle about of 128 °. This study can guide the fabrication and modeling of highly designable and customized DE actuators, which are promising in the applications of soft robotics, flexible electronics, and medical devices.

Fabrication and modeling of dielectric elastomer soft actuator with 3D printed thermoplastic frame

Soft robots driven by stimuli-responsive materials have their own unique advantages over traditional rigid robots such as large actuation, light weight, good flexibility and biocompatibility. However, the large actuation of soft robots inherently co-exists with difficulty in control with high precision. This article presents a soft artificial muscle driven robot mimicking cuttlefish with a fully integrated on-board system including power supply and wireless communication system. Without any motors, the movements of the cuttlefish robot are solely actuated by dielectric elastomer which exhibits muscle-like properties including large deformation and high energy density. Reinforcement learning is used to optimize the control strategy of the cuttlefish robot instead of manual adjustment. From scratch, the swimming speed of the robot is enhanced by 91% with reinforcement learning, reaching to 21 mm/s (0.38 body length per second). The design principle behind the structure and the control of the robot can be potentially useful in guiding device designs for demanding applications such as flexible devices and soft robots.

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A soft artificial muscle driven robot with reinforcement learning.

For decades, the water deficit has been a severe global issue. A reliable supply of water is needed to ensure sustainable economic development in population growth, industrialization and urbanization. To solve this major challenge, membrane-based water treatment technology has attracted a great deal of attention to produce clean drinking water from groundwater, seawater and brackish water. The emergence of nanotechnology in membrane science has opened new frontiers in the development of advanced polymeric membranes to enhance filtration performance. Nevertheless, some obstacles such as fouling and trade-off of membrane selectivity and permeability of water have hindered the development of traditional polymeric membranes for real applications. To overcome these issues, the modification of membranes has been pursued. The use of macromolecules for membrane modification has attracted wide interests in recent years owing to their interesting chemical and structural properties. Membranes modified with macromolecules have exhibited improved anti-fouling properties due to the alteration of their physiochemical properties in terms of the membrane morphology, porosity, surface charge, wettability, and durability. This review provides a comprehensive review of the progress made in the development of macromolecule modified polymeric membranes. The role of macromolecules in polymeric membranes and the advancement of these membrane materials for water solution are presented. The challenges and future directions for this subject are highlighted.

Tuck Whye Wong

Papers

Untethered soft robotic jellyfish

Fabrication and modeling of dielectric elastomer soft actuator with 3D printed thermoplastic frame

A soft artificial muscle driven robot with reinforcement learning.

The Recent Progress in Modification of Polymeric Membranes Using Organic Macromolecules for Water Treatment

Water transport properties of boron nitride nanosheets mixed matrix membranes for humic acid removal.