Concentrated solar thermal power generation is becoming a very attractive renewable energy production system among all the different renewable options, as it has have a better potential for dispatchability. This dispatchability is inevitably linked with an efficient and cost-effective thermal storage system. Thus, of all components, thermal storage is a key one. However, it is also one of the less developed. Only a few plants in the world have tested high temperature thermal energy storage systems. In this paper, the different storage concepts are reviewed and classified. All materials considered in literature or plants are listed. And finally, modellization of such systems is reviewed.

State of the art on high temperature thermal energy storage for power generation. Part 1—Concepts, materials and modellization

Thermal energy storage technologies and systems for concentrating solar power plants

The development of energy saving technologies is very actual issue of present day. One of perspective directions in developing these technologies is the thermal energy storage in various industry branches. The review considers the modern state of art in investigations and developments of high-temperature phase change materials perspective for storage thermal and a solar energy in the range of temperatures from 120 to 1000 °C. The considerable quantity of mixes and compositions on the basis of fluorides, chlorides, hydroxides, nitrates, carbonates, vanadates, molybdates and other salts, and also metal alloys is given. Thermophysical properties of potential heat storage salt compositions and metal alloys are presented. Compatibility of heat storage materials (HSM) and constructional materials have found its reflection in the present work. Data on long-term characteristics of some HSMs in the course of repeated cycles of fusion and solidification are analyzed. Article considers also other problems which should be solved for creation of commercial high-temperature heat storage devices with use of phase change materials.

High-temperature phase change materials for thermal energy storage

This paper presents an overview of the parabolic-trough collectors that have been built and marketed during the past century, as well as the prototypes currently under development. It also presents a survey of systems which could incorporate this type of concentrating solar system to supply thermal energy up to 400 °C, especially steam power cycles for electricity generation, including examples of each application.

Parabolic-trough solar collectors and their applications

Power generation systems are attracting a lot of interest from researchers and companies. Storage is becoming a component with high importance to ensure system reliability and economic profitability. A few experiences of storage components have taken place until the moment in solar power plants, most of them as research initiatives. In this paper, real experiences with active storage systems and passive storage systems are compiled, giving detailed information of advantages and disadvantages of each one. Also, a summary of different technologies and materials used in solar power plants with thermal storage systems existing in the world is presented.

State of the art on high-temperature thermal energy storage for power generation. Part 2—Case studies

Two-tank molten salt storage for parabolic trough solar power plants

An evaluation was carried out to investigate the feasibility of utilizing a molten salt as the heat transfer fluid (HTF) and for thermal storage in a parabolic trough solar field to improve system performance and to reduce the levelized electricity cost. The operating SEGS (Solar Electric Generating Systems located in Mojave Desert, California) plants currently use a high temperature synthetic oil consisting of a eutectic mixture of biphenyl/ diphenyl oxide. The scope of this investigation included examination of known critical issues, postulating solutions or possible approaches where potential problems exist, and the quantification of performance and electricity cost using preliminary cost inputs. The two leading candidates were the so-called solar salt (a binary salt consisting of 60% NaNO 3 and 40% KNO 3 ) and a salt sold commercially as HitecXL (a ternary salt consisting of 48% Ca(NO 3 ) 2 , 7% NaNO 3 , and 45% KNO 3 ). Assuming a two-tank storage system and a maximum operation temperature of 450°C, the evaluation showed that the levelized electricity cost can be reduced by 14.2% compared to a state-of-the-art parabolic trough plant such as the SEGS plants. If higher temperatures are possible, the improvement may be as high as 17.6%. Thermocline salt storage systems offer even greater benefits.

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Assessment of a Molten Salt Heat Transfer Fluid in a Parabolic Trough Solar Field

A literature review was carried out to critically evaluate the state of the art of thermal energy storage applied to parabolic trough power plants. This survey briefly describes the work done before 1990 followed by a more detailed discussion of later efforts. The most advanced system is a 2-tank-storage system where the heat transfer fluid (HTF) also serves as storage medium. This concept was successfully demonstrated in a commercial trough plant (13.8 MW e SEGS I plant; 120 MWh t storage capacity) and a demonstration tower plant (10 MW e Solar Two; 105 MWh t storage capacity). However, the HTF used in state-of-the-art parabolic trough power plants (30-80 MW e ) is expensive, dramatically increasing the cost of larger HTF storage systems. Other promising storage concepts are under development, such as concrete storage, phase change material storage, and chemical storage. These concepts promise a considerable cost reduction compared to the direct 2-tank system, but some additional R&D is required before those systems can be used in commercial solar power plants. An interesting and likely cost-effective near-term option for thermal energy storage for parabolic trough power plants is the use of an indirect 2-tank-storage, where another (less expensive) liquid medium such as molten salt is utilized rather than the HTF itself.

Ulf Herrmann

Papers

Two-tank molten salt storage for parabolic trough solar power plants

Assessment of a Molten Salt Heat Transfer Fluid in a Parabolic Trough Solar Field

Survey of Thermal Energy Storage for Parabolic Trough Power Plants

Engineering aspects of a molten salt heat transfer fluid in a trough solar field

Trough integration into power plants : a study on the performance and economy of integrated solar combined cycle systems