Organotin compounds are ubiquitous contaminants in the environment. The high biological activity of some compounds toward aquatic organisms lead to deleterious impacts in aquatic ecosystems. Here, the aquatic ecotoxicology of organotins is reviewed based on a multidisciplinary approach involving environmental chemical, toxicological, and ecological aspects. Basic results were obtained both with field and laboratory studies, and some of the most important recent results and conclusions are critically reviewed. The contamination of and fate in aquatic systems is reported and linked with effects at different levels of biological organization. Major emphasis is placed on the development of a concept of ecotoxicology that encompasses not only effect assessment alone, but also integrates environmental chemistry with aquatic toxicology. Thereby, the influence of speciation for bioavailability, basic modes of toxic action, and aquatic toxicity are discussed. This case study on organotins allows to a certain extent generalizations to ecotoxicology in general.

Ecotoxicology of organotin compounds.

The removal of dyes from textile wastewater: a study of the physical characteristics and adsorption mechanisms of diatomaceous earth

This public health statement tells you about manganese and the effects of exposure to it.The Environmental Protection Agency (EPA) identifies the most serious hazardous waste sites in the nation. These sites are then placed on the National Priorities List (NPL) and are targeted for long-term federal clean-up activities. Manganese has been found in at least 869 of the 1,699 current or former NPL sites. Although the total number of NPL sites evaluated for this substance is not known, the possibility exists that the number of sites at which manganese is found may increase in the future as more sites are evaluated. This information is important because these sites may be sources of exposure and exposure to this substance may harm you.When a substance is released either from a large area, such as an industrial plant, or from a container, such as a drum or bottle, it enters the environment. Such a release does not always lead to exposure. You can be exposed to a substance only when you come in contact with it. You may be exposed by breathing, eating, or drinking the substance, or by skin contact.If you are exposed to manganese, many factors will determine whether you will be harmed. These factors include the dose (how much), the duration (how long), and how you come in contact with it. You must also consider any other chemicals you are exposed to and your age, sex, diet, family traits, lifestyle, and state of health.

Toxicological Profile for Manganese

Amino acid analysis : Hydrolysis, ion-exchange cleanup, derivatization, and quantitation by gas—liquid chromatography

Nanoparticles (NPs), due to their unique physical and chemical properties, especially their minute particle size (⩽100 nm), find applications in numerous industrial, commercial and consumer products. After their end-user applications, these NPs find their way into the environment and food products. The NPs so discharged need to be quantified accurately to determine their toxicity and exposure levels. At this time, there is a need to develop a unified method for their determination. There are plenty of techniques available in the market that were initially used for colloidal particles (e.g., microscopy, spectroscopy and the recent addition of magnetic resonance), but each of these techniques has a certain degree of uncertainty. Further, sample homogeneity, sample preparation, instrument-operating procedures, and statistical practices are likely to add to the complexity of the problem. In this context, this review attempts to understand the widely-used light-scattering techniques, including their theory, practice and real-world use in determination of NPs in environmental and food applications.

Measurement of nanoparticles by light-scattering techniques

Influence of silanol groups on the bonding of Carbowax 20M

To know the spatial distribution of ion pairs resulting from 63Ni β radiation in the gas phase is important for a variety of theoretical and practical reasons, in particular those concerning the electron capture detector. Literature estimates of this distribution vary by about one order of magnitude, yet this parameter is necessary for the modelling of this detector. The 63Ni-induced, initial ion pair distribution was therefore measured in a variety of gases with two techniques: a conventional one based on the electrical saturation current at variable interelectrode distances, and an unconventional one based on luminescence from a plastic scintillator. The data are analyzed in terms of two ranges, d50 and d95, that describe the distances from a planar radioactive foil within which 50% and 95% of the total gas-phase ionization occur. The data from the electrical measurement show unexpected evidence of strong β backscattering and secondary electron emission from the counter-electrode. Under these (non-expon...

Walter A. Aue

Papers

Influence of silanol groups on the bonding of Carbowax 20M

63Ni β range and backscattering in confined geometries

Chemiluminescent emission spectra of lead, chromium, ruthenium, iron, manganese, rhenium, osmium and tungsten in the reactive flow detector

Constancy of spectral response ratios in the flame photometric detector

Determination of methane arsonic acid by gas-liquid chromatography