Wim Dermaut

TL;DR: In this paper, an efficient continuous-flow procedure for the synthesis of tribromomethylsulfones and tribrommethanesulfonates has been developed starting from the corresponding methylsulfone or methanesulfone and potassium hypobromite using a biphasic reaction.

TL;DR: In this paper, the authors used the nonparametric kinetic modelling approach as provided in the Advanced Kinetics and Technology Solutions software package to determine the decomposition behavior of cyanamide. But the model was constructed on the basis of five different DSC runs, each with a different heating rate, and its validity was checked through a comparison of the predicted adiabatic runaway profile with the results of actual adiabeatic experiments in the Phi-Tec calorimeter.

TL;DR: Chloroformylation reactions are versatile reactions that allow the introduction of a chlorine atom and an aldehyde group in enolizable ketones, employing the well-known Vilsmeier reagent.

TL;DR: In this article, the authors describe a possible way of simulating the behavior at φ = 1 in test cells with higher thermal inertia, which consists of leaving out an amount of solvent which matches exactly the thermal mass of the measuring cell.

TL;DR: In this paper, two alternative synthesis routes for the preparation of N-phenyl acrylamide, but applicable as a continuous production process, are presented: both based on the Schotten-Baumann reaction, one starting from 3-chloropropanoyl chloride and the other starting from acrylic acid.