As one unique group of two-dimensional (2D) nanomaterials, 2D metal nanomaterials have drawn increasing attention owing to their intriguing physiochemical properties and broad range of promising applications. In this Review, we briefly introduce the general synthetic strategies applied to 2D metal nanomaterials, followed by describing in detail the various synthetic methods classified in two categories, i.e. bottom-up methods and top-down methods. After introducing the unique physical and chemical properties of 2D metal nanomaterials, the potential applications of 2D metal nanomaterials in catalysis, surface enhanced Raman scattering, sensing, bioimaging, solar cells, and photothermal therapy are discussed in detail. Finally, the challenges and opportunities in this promising research area are proposed.

Two-Dimensional Metal Nanomaterials: Synthesis, Properties, and Applications

Nanoparticles and nanofibers for topical drug delivery.

Quantum dots (QDs) derived from the atomically-thin two-dimensional (2D) sheets (graphene, transition metal dichalcogenide, graphitic carbon nitride, hexagonal boron nitride, and phosphorene) are emerging extraordinary zero-dimensional materials. Covering a broad spectrum of interesting optical, catalytic, electronic, chemical and electrochemical properties, these 2D-QDs promise a wide range of novel applications including imaging, sensing, cancer therapy, optoelectronics, display, catalysis, and energy. In this article, we discuss the synthesis methods and the properties of these 2D-QDs and emphasize their applications in electrocatalysis, photocatalysis, supercapacitors, batteries, and photovoltaics.

Quantum dots derived from two-dimensional materials and their applications for catalysis and energy

Modern electronics based on semiconductors is meeting the fundamental speed limit caused by the interconnect delay and large heat generation when the sizes of components reach nanometer scale. Photons as a carrier of the information are superior to electrons in bandwidth, density, speed, and dissipation. More over, photons could carry intensity, polarization, phase, and frequency information which could break through the limitation of binary system as in electronic devices. But due to the diffraction limitation, the photonic components and devices can not be fabricated small enough to be integrated densely. Surface plasmon polariton is quanta of collective oscillations of free electrons excited by photons in metal nanostrucrures, which offers a promising way to manipulate light at the nanoscale and to realize the miniaturization of photonic devices. Hence, plasmonic circuits and devices have been proposed for some time as a potential strategy for advancing semiconductor-based computing beyond the fundamental performance limitations of electronic devices, as epitomized by Moore's law. A variety of individual plasmonic nanodevices have been intensively studied recently, but the crucial and necessary step to enable nanophotonic circuits for future information technology, namely cascade logics integrated on-chip, has not been achieved. Here we demonstrate that a nanophotonic binary logic NOR gate can be realized by cascading plasmonic OR and NOT gates in four-terminal nanowire networks. We explain the operating principle for the device based on quantum dot luminescence imaging, which reveal the interferences for different logic functions between propagating plasmon wave packets in the nanowire network in great detail. Since the NOR gate is logic complete, i.e. any Boolean logic gate can be constructed from it, our results could have a key role in defining a viable path for the development of novel subwavelength optical processor architectures.

Cascaded Logic Gates in Nanophotonic Plasmon Networks

: Plasmon lasers are a new class of coherent optical frequency electromagnetic wave amplifiers that deliver intense coherent and directional surface plasmons well below the diffraction barrier. The strongly confined electric fields in plasmon lasers can enhance significantly light-matter interactions and bring fundamentally new capabilities to bio-sensing, data storage photolithography and optical communications.

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Plasmon lasers: coherent light source at molecular scales

We describe a rapid, simple, room-temperature technique for the production of large-scale metallic thin films with tunable plasmonic properties assembled from size-selected silver nanoplates (SNPs). We outline the properties of a series of ultrathin monolayer metallic films (8-20 nm) self-assembled on glass substrates in which the localized surface plasmon resonance can be tuned over a range from 500 to 800 nm. It is found that the resonance peaks of the films are strongly dependent on the size of the nanoplates and the refractive index of the surrounding dielectric. It is also shown that the bandwidth and the resonance peak of the plasmon resonance spectrum of the metallic films can be engineered by simply controlling aggregation of the SNP. A three-dimensional finite element method was used to investigate the plasmon resonance properties for individual SNPs in different dielectrics and plasmon coupling in SNP aggregates. A 5-17 times enhancement of scattering from these SNP films has been observed experimentally. Our experimental results, together with numerical simulations, indicate that this self-assembly method shows great promise in the production of nanoscale metallic films with enormous electric-field enhancements at visible and near-infrared wavelengths. These may be utilized in biochemical sensing, solar photovoltaic, and optical processing applications.

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Self-Assembly of Large-Scale and Ultrathin Silver Nanoplate Films with Tunable Plasmon Resonance Properties

Serving as shape control agent, polyvinyl pyrrolidone (PVP) has been widely used in chemical synthesis of metal nanoparticles. However, the role of molecular weight (MW) of PVP has been rarely concerned. In this study, we show a facile method to control the shapes of silver nanocrystals using PVP with different MWs. PVPMW=8,000, PVPMW=29,000, PVPMW=40,000, and PVPMW=1,300,000 are compared in the present study. Surprisingly, high-yield silver rodlike nanostructures, nanospheres, and nanowires can be obtained under the same growth environment and reactant concentrations by simply changing the MW of PVP. The mechanism studies of the role of PVP with different MWs in the growth process were carried out systemically using the morphology and spectroscopic measurement, FT-IR spectrum analysis, and seed crystallization monitoring. The results indicate that the MW of PVP plays a determinant role in the morphology and optical property control of the silver nanocrystals. Meantime, the concentration of PVP was found to be an assistant factor to further improve the shape and the yield of the synthesized nanocrystals.

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Investigation on the role of the molecular weight of polyvinyl pyrrolidone in the shape control of high-yield silver nanospheres and nanowires

We report the first study of nanoscale integrated photonic devices constructed with semiconductor-insulator-metal strip (SIMS) waveguides for use at telecom wavelengths. These waveguides support hybrid plasmonic modes transmitting through a 5-nm thick insulating region with a normalized intensity of 200-300 μm−2. Their fundamental mode, unique transmission and dispersion properties are consistent with photonic devices for guiding and routing of signals in communication applications. It has been demonstrated using Finite Element Methods (FEM) that the high performance SIMS waveguide can be used to fabricate deep sub-wavelength integrated plasmonic devices such as directional couplers with the ultra short coupling lengths, sharply bent waveguides, and ring resonators having a functional size of ≈1 µm and with low insertion losses and nearly zero radiation losses.

http://www.me.uwaterloo.ca/~camj/pdf/OP1.pdf

Numerical analysis of deep sub-wavelength integrated plasmonic devices based on Semiconductor-Insulator-Metal strip waveguides

The shape of plasmonic nanostructures such as silver and gold is vital to their physical and chemical properties and potential applications. Recently, preparation of complex nanostructures with rich function by chemical multistep methods is the hotspot of research. In this review we introduce three typical multistep methods to prepare silver nanostructures with well-controlled shapes, including the double reductant method, etching technique and construction of core-shell nanostructures. The growth mechanism of double the reductant method is that different favorable facets of silver nanocrystals are produced in different reductants, which can be used to prepare complex nanostructures such as nanoflags with ultranarrow resonant band bandwidth or some silver nanostructures which are difficult to prepare using other methods. The etching technique can selectively remove nanoparticles to achieve the aim of shape control and is widely used for the synthesis of nanoflowers and hollow nanostructures. Construction of core-shell nanostructures is another tool to control shape and size. The three methods can not only prepare various silver nanostructures with well-controlled shapes, which exhibit unique optical properties, such as strong surface-enhanced Raman scattering (SERS) signal and localized surface plasmon resonance (LSPR) effect, but also have potential application in many areas.

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Synthesis of silver nanostructures by multistep methods.

We report a sonication combined with ion intercalation method in an alkaline environment to fabricate MoS2 quantum dots (QDs), with the quantum-yield of the QDs increasing from 0.99% to 4.84% with the additive sodium hydroxide. The QDs displaying variable photoluminescence emission were systematically studied and applied to the bio-imaging field.

Xiao-Yang Zhang

Papers

Self-Assembly of Large-Scale and Ultrathin Silver Nanoplate Films with Tunable Plasmon Resonance Properties

Investigation on the role of the molecular weight of polyvinyl pyrrolidone in the shape control of high-yield silver nanospheres and nanowires

Numerical analysis of deep sub-wavelength integrated plasmonic devices based on Semiconductor-Insulator-Metal strip waveguides

Synthesis of silver nanostructures by multistep methods.

High quantum-yield luminescent MoS2 quantum dots with variable light emission created via direct ultrasonic exfoliation of MoS2 nanosheets