Applications of nanotechnology in water and wastewater treatment

Evaluation of advanced oxidation processes for water and wastewater treatment - A critical review.

Graphene-based materials are gaining heightened attention as novel materials for environmental applications The unique physicochemical properties of graphene, notably its exceptionally high surface area, electron mobility, thermal conductivity, and mechanical strength, can lead to novel or improved technologies to address the pressing global environmental challenges This critical review assesses the recent developments in the use of graphene-based materials as sorbent or photocatalytic materials for environmental decontamination, as building blocks for next generation water treatment and desalination membranes, and as electrode materials for contaminant monitoring or removal The most promising areas of research are highlighted, with a discussion of the main challenges that we need to overcome in order to fully realize the exceptional properties of graphene in environmental applications

Environmental applications of graphene-based nanomaterials.

The controversy related to the environment pollution is increasing in human life and in the eco-system. Especially, the water pollution is growing rapidly due to the wastewater discharge from the industries. The only way to find the new water resource is the reuse of treated wastewater. Several remediation technologies are available which provides a convenience to reuse the reclaimed wastewater. Heavy metals like Zn, Cu, Pb, Ni, Cd, Hg, etc. contributes various environmental problems based on their toxicity. These toxic metals are exposed to human and environment, the accumulation of ions takes place which causes serious health and environmental hazards. Hence, it is a major concern in the environment. Due to this concern, the significance of developing technology for removing heavy metals has been increased. This paper contributes the outline of new literature with two objectives. First, it provides the sketch about treatment technologies followed by their heavy metal capture capacity from industrial effluent. The treatment performance, their remediation capacity and probable environmental and health impacts were deliberated in this review article. Conclusively, this review paper furnishes the information about the important methods incorporated in lab scale studies which are required to identify the feasible and convenient wastewater treatment. Moreover, attempts have been made to confer the emphasis on sequestration of heavy metals from industrial effluent and establish the scientific background for reducing the discharge of heavy metals into the environment.

Efficient techniques for the removal of toxic heavy metals from aquatic environment: A review

Heavy metal removal from aqueous solution by advanced carbon nanotubes: Critical review of adsorption applications

Hydrophobicity of natural organic matter (NOM) is one of its fundamental properties that influence the environmental fate of pollutants and the performance of many water treatment unit processes. In this study, a high-throughput method was developed for NOM hydrophobicity measurement based on the phase separation technique in the 96-well format. It measures the partition coefficients of NOM (KATPS,IL) in an ionic liquid (IL)-based aqueous two-phase system (ATPS). The ATPS was made of 1-butyl-3-methylimidazole bromide solution and a salt solution containing potassium phosphate monobasic and potassium phosphate dibasic. The partition of NOM in IL-based ATPS is mainly affected by its hydrophobicity. log KATPS,IL linearly correlated with the commonly used NOM hydrophobicity scales, including (O + N)/C, O/C, and aromatic carbons. KATPS,IL provided a more accurate assessment of NOM hydrophobicity than spectroscopic indices. Furthermore, KATPS,IL can predict the organic carbon-water partition coefficients for hydrophobic organic chemical sorption to NOM based on the two-phase system model. The high-throughput KATPS,IL measurement and the two-phase system model can be applied to real surface water samples. Our results suggest that the proposed high-throughput method has great potential to be applied to monitor NOM hydrophobicity for environmental risk assessment and water treatment purposes.

High-Throughput Method for Natural Organic Matter Hydrophobicity Assessment Using an Ionic Liquid-Based Aqueous Two-Phase System.

Novel phosphate adsorbents with confined La2O3 inside mesoporous carbon were fabricated by the solid-state grinding method using pristine mesoporous carbon material CMK-3 (PCMK-3) and oxidized CMK-...

https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.210428

Confined La2O3 particles in mesoporous carbon material for enhanced phosphate adsorption

The Three Gorges Dam (TGD) is the largest hydropower facility in the world, influencing the riverine hydrology and mass flux in the Yangtze River. Little is known about its impact on the riverine dissolved organic matter (DOM) quality. In this work, the water quality and DOM quality for water samples collected from the upstream and downstream sites of TGD were investigated. The presence of TGD significantly affects the quantity and quality of DOM but has no pronounced effect on nutrient concentrations. Upstream DOM had higher concentration but lower average molecular weight and aromaticity than the downstream DOM. The biological processes in the dam reservoir contribute significantly to upstream DOM. In the downstream sites, terrestrial DOM input raises the average molecular weight and aromaticity of the overall DOM pool. These results suggest that TGD will influence not only the mass flux of organic carbon but also its quality and lability, which has both environmental and ecological significance.

Impact of the Three Gorges Dam on the Quality of Riverine Dissolved Organic Matter.

Selective binding of organic compounds is the cornerstone of many important industrial and pharmaceutical applications. Here, we achieved highly selective binding of aromatic compounds in aqueous solution and gas phase by oxygen-enriched graphene oxide (GO) nanosheets via a previously unknown mechanism based on size matching and polarity matching. Oxygen-containing functional groups (predominately epoxies and hydroxyls) on the nongraphitized aliphatic carbons of the basal plane of GO formed highly polar regions that encompass graphitic regions slightly larger than the benzene ring. This facilitated size match–based interactions between small apolar compounds and the isolated aromatic region of GO, resulting in high binding selectivity relative to larger apolar compounds. The interactions between the functional group(s) of polar aromatics and the epoxy/hydroxyl groups around the isolated aromatic region of GO enhanced binding selectivity relative to similar-sized apolar aromatics. These findings provide opportunities for precision separations and molecular recognition enabled by size/polarity match–based selectivity.

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Xiaolei Qu

Papers

High-Throughput Method for Natural Organic Matter Hydrophobicity Assessment Using an Ionic Liquid-Based Aqueous Two-Phase System.

Confined La2O3 particles in mesoporous carbon material for enhanced phosphate adsorption

Impact of the Three Gorges Dam on the Quality of Riverine Dissolved Organic Matter.

Mechanism for selective binding of aromatic compounds on oxygen-rich graphene nanosheets based on molecule size/polarity matching

Prediction of hydrophobic organic compound partition to algal organic matter through the growth cycle of Microcystis aeruginosa.