Ege University

About: Ege University is a education organization based out in Izmir, Turkey. It is known for research contribution in the topics: Population & Medicine. The organization has 10166 authors who have published 22035 publications receiving 429516 citations.

Time Synchronization Based on Slow-Flooding in Wireless Sensor Networks

Abstract: The accurate and efficient operation of many applications and protocols in wireless sensor networks require synchronized notion of time. To achieve network-wide time synchronization, a common strategy is to flood current time information of a reference node into the network, which is utilized by the de facto time-synchronization protocol Flooding Time-Synchronization Protocol (FTSP). In FTSP, the propagation speed of the flood is slow because each node waits for a given period of time to propagate its time information about the reference node. It has been shown that slow-flooding decreases the synchronization accuracy and scalability of FTSP drastically. Alternatively, rapid-flooding approach is proposed in the literature, which allows nodes to propagate time information as quickly as possible. However, rapid flooding is difficult and has several drawbacks in wireless sensor networks. In this paper, our aim is to reduce the undesired effect of slow-flooding on the synchronization accuracy without changing the propagation speed of the flood. Within this context, we realize that the smaller the difference between the speeds of the clocks, the smaller the undesired effect of waiting times on the synchronization accuracy. In the light of this realization, our main contribution is to show that the synchronization accuracy and scalability of slow-flooding can drastically be improved by employing a clock speed agreement algorithm among the sensor nodes. We present an evaluation of this strategy on a testbed setup including 20 MICAz sensor nodes. Our theoretical findings and experimental results show that employing a clock speed agreement algorithm among the sensor nodes drastically improves the synchronization accuracy and scalability of slow-flooding.

η6‐Mesityl,η1‐Imidazolinylidene–Carbene–Ruthenium(II) Complexes: Catalytic Activity of their Allenylidene Derivatives in Alkene Metathesis and Cycloisomerisation Reactions

Abstract: The reaction of electron-rich carbene-precursor olefins containing two imidazolinylidene moieties [(2,4,6-Me(3)C(6)H(2)CH(2))NCH(2)CH(2)N(R)Cdbond;](2) (2a: R=CH(2)CH(2)OMe, 2 b R=CH(2)Mes), bearing at least one 2,4,6-trimethylbenzyl (R=CH(2)Mes) group on the nitrogen atom, with [RuCl(2)(arene)](2) (arene=p-cymene, hexamethylbenzene) selectively leads to two types of complexes. The cleavage of the chloride bridges occurs first to yield the expected (carbene) (arene)ruthenium(II) complex 3. Then a further arene displacement reaction takes place to give the chelated eta(6)-mesityl,eta(1)-carbene-ruthenium complexes 4 and 5. An analogous eta(6)-arene,eta(1)-carbene complex with a benzimidazole frame 6 was isolated from an in situ reaction between [RuCl(2)(p-cymene)](2), the corresponding benzimidazolium salt and cesium carbonate. On heating, the RuCl(2)(imidazolinylidene) (p-cymene) complex 8, with p-methoxybenzyl pendent groups attached to the N atoms, leads to intramolecular p-cymene displacement and to the chelated eta(6)-arene,eta(1)-carbene complex 9. On reaction with AgOTf and the propargylic alcohol HCtbond;CCPh(2)OH, compounds 4-6 were transformed into the corresponding ruthenium allenylidene intermediates (4-->10, 5-->11, 6-->12). The in situ generated intermediates 10-12 were found to be active and selective catalysts for ring-closing metathesis (RCM) or cycloisomerisation reactions depending on the nature of the 1,6-dienes. Two complexes [RuCl(2)[eta(1)-CN(CH(2)C(6)H(2)Me(3)-2,4,6)CH(2)CH(2)N- (CH(2)CH(2)OMe)](C(6)Me(6))] 3 with a monodentate carbene ligand and [RuCl(2)[eta(1)-CN[CH(2)(eta(6)-C(6)H(2)Me(3)-2,4,6)]CH(2)CH(2)N-(CH(2)C(6)H(2)Me(3)-2,4,6)]] 5 with a chelating carbene-arene ligand were characterised by X-ray crystallography.

Search for dijet resonances in 7 TeV pp collisions at CMS

Abstract: A search for narrow resonances in the dijet mass spectrum is performed using data corresponding to an integrated luminosity of 2.9 inverse pb collected by the CMS experiment at the LHC. Upper limits at the 95% confidence level (CL) are presented on the product of the resonance cross section, branching fraction into dijets, and acceptance, separately for decays into quark-quark, quark-gluon, or gluon-gluon pairs. The data exclude new particles predicted in the following models at the 95% CL: string resonances, with mass less than 2.50 TeV, excited quarks, with mass less than 1.58 TeV, and axigluons, colorons, and E_6 diquarks, in specific mass intervals. This extends previously published limits on these models.