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Showing papers in "Inorganic and Nano-Metal Chemistry in 2019"


Journal ArticleDOI
TL;DR: In this paper, the average diameter size of AgNPs induced by Penicillium citrinum was optimized by using response surface methodology (RSM) and Box-Behnken design (BBD).
Abstract: The objective of current study was to optimize the average diameter size of biosynthesized Silver Nanoparticles (AgNPs) induced by Penicillium citrinum. The AgNPs were prepared with a spherical shape and good monodispersity, determined by scanning electron microscopy (SEM), atomic force microscopy (AFM) and photon correlation spectroscopy (PCS). Besides, response surface methodology (RSM) was conducted to optimize the average diameter size of AgNPs by employing Box-Behnken design (BBD). The effective factors in this process were concentration of AgNO3 (mM) (X1), pH of solution (X2), temperature of shaker incubator (°C) (X3), rate of shaker incubator (rpm) (X4) and time of incubation (hour) (X5). The R2 (0.8894) value of the obtained model indicated a good correlation between the observed and predicted values. Overall, it could be concluded that multivariate analysis facilitated to find out the optimum conditions for the biosynthesis of AgNPs induced by P. citrinum with the reduced time and cost.

69 citations


Journal ArticleDOI
TL;DR: In this article, the synthesis of ZnO nanoparticles (NPs) using leaf extract of P... is presented. But the method is not suitable for the application of medical applications.
Abstract: Nanoparticle synthesis using plants is an alternative to conventional physical and chemical methods. In this article, we demonstrate the synthesis of ZnO nanoparticles (NPs) using leaf extract of P...

25 citations


Journal ArticleDOI
TL;DR: In this paper, the Nitrogen dioxide (NO2) gas sensing properties of the nanogrannular Titanium dioxide (TiO2) thin films synthesized on a glass substrate using simplis...
Abstract: The present investigation reports on the Nitrogen dioxide (NO2) gas sensing properties of the nanogrannular Titanium dioxide (TiO2) thin films synthesized on a glass substrate using simplis...

25 citations


Journal ArticleDOI
TL;DR: In this paper, the authors employed Stevia rebaudiana leaves for the first time for synthesis and stabilization of ZnO nanoparticles, which is a well-known medicinal plant for its noncaloric bio-sweetener.
Abstract: Stevia rebaudiana leaves is a well-known medicinal plant for its non-caloric bio-sweetener. To enhance its value addition, employed first time for synthesis and stabilization of ZnO nanoparticles. ...

14 citations


Journal ArticleDOI
TL;DR: In this article, SBA-15 mesoporous nanoparticles were synthesized by hydrothermal method and functionalized with amino group by post grafting method (SBA 15-NH2), then thymol was loaded into S...
Abstract: In the present study, SBA-15 mesoporous nanoparticles were synthesized by hydrothermal method and functionalized with amino group by post grafting method (SBA-15-NH2), then thymol was loaded into S...

14 citations


Journal ArticleDOI
TL;DR: In this article, thermochromic VO2 thin films were prepared on quartz substrates with sol-gel method, and Vanadium oxide films were annealed at 550°C for 4'h in a tube furnace within a nitrogen atmosphere.
Abstract: Thermochromic VO2 thin films were prepared on quartz substrates with sol–gel method. After the Vanadium oxide films were annealed at 550 °C for 4 h in a tube furnace within a nitrogen atmosphere, M...

14 citations


Journal ArticleDOI
TL;DR: In this paper, a nano scavenger of [C16H33N(CH3)3]7H3[P2W18Cd4O68]@TiO2 was used for desulfurization of gas oil.
Abstract: Oxidative desulfurization of gas oil and model compounds that exist in gas oil with acetic acid/hydrogen peroxide using nanoparticle of [C16H33N(CH3)3]7H3[P2W18Cd4O68]@TiO2 as a nano scaven...

13 citations


Journal ArticleDOI
TL;DR: In this article, a green and environmentally benign method for synthesizing zinc oxide nanoparticles (ZnO NPs) using aqueous extract of dragon fruit (Hylocereus polyrhizus) peel biowaste a...
Abstract: This work reports a green and environmentally benign method for synthesizing zinc oxide nanoparticles (ZnO NPs) using aqueous extract of dragon fruit (Hylocereus polyrhizus) peel biowaste a...

12 citations


Journal ArticleDOI
TL;DR: Copper oxide nanoparticles (CuO NPs) were synthesized from the methanolic extract of Prunus amygdalus pericarp as discussed by the authors, and the presence of Phytocompounds such as tetrahydroaraucarlone, Prostaglandin A2, Molyb...
Abstract: Copper oxide nanoparticles (CuO NPs) were synthesized from the methanolic extract of Prunus amygdalus pericarp. The presence of Phytocompounds such as tetrahydroaraucarlone, Prostaglandin A2, Molyb...

12 citations


Journal ArticleDOI
TL;DR: In this paper, the copper/silver couple was fabricated via diffusion bonding process with the aid of nickel and silver foils as interlayers, and the results indicated the width of reaction layer of interfaces was inc...
Abstract: The Copper/Silver couple was fabricated via diffusion bonding process with the aid of nickel and silver foils as interlayers. The results indicated the width of reaction layer of interfaces was inc...

12 citations


Journal ArticleDOI
TL;DR: In this article, a nanocomposite cotton fabrics with in situ generated copper nanoparticles (CuNPs) were prepared using Pterocarpus santalinus (Red sanders) aqueous extraction as a reducing agent.
Abstract: Nanocomposite cotton fabrics with in situ generated copper nanoparticles (CuNPs) were prepared using Pterocarpus santalinus (Red sanders) aqueous extraction as a reducing agent. The nanocomposite c...

Journal ArticleDOI
TL;DR: In this paper, the exploitation of various plant materials for the synthesis of nanoparticles is considered as a green technology as it does not necessitate any hazardous chemicals, and the authors report the syn...
Abstract: The exploitation of various plant materials for the synthesis of nanoparticles is considered as a green technology as it does not necessitate any hazardous chemicals. Here we report the syn...

Journal ArticleDOI
TL;DR: A zinc(II) metal-organic framework, [Zn (BDC) (MI) (DMF) or Zn-MOF] has been synthesized by solvothermal met... as discussed by the authors.
Abstract: A zinc(II) metal-organic framework, [Zn (BDC) (MI) (DMF) or Zn-MOF] (BDC=Benzene 1, 4 di-carboxylic acid, MI=Methylimidazole and DMF=N, N-dimethylformamide) has been synthesized by solvothermal met...

Journal ArticleDOI
TL;DR: The stiffness and protein adsorption were enhanced in PCL/CNTs substrate and cell proliferation enhanced in these composite substrates.
Abstract: Bone marrow stem cells attracted much attention for cell transplantation therapy of neurodegenerative diseases and injuries of the nervous system. Because of the easy access and the ability of thes...

Journal ArticleDOI
TL;DR: In this paper, the adaptation behavior of acid black 210 (AB210) and Remazol Brilliant Blue R (RBBR) from aqueous solutions onto magnetite nanoparticles (MNPs) was studied.
Abstract: Adsorption behavior of Acid Black 210 (AB210) and Remazol Brilliant Blue R (RBBR) from aqueous solutions onto magnetite nanoparticles (MNPs) was studied. Affecting parameters such as solution pH, c...

Journal ArticleDOI
TL;DR: In this paper, ultrasonic spray deposition was successfully employed to the synthesis of ZnO thin films, then found that it can be suitable for application as a transparent conducting electrode.
Abstract: Ultrasonic spray deposition was successfully employed to the synthesis of ZnO thin films, then found that can be suitable for application as a transparent conducting electrode. The effects of subst...

Journal ArticleDOI
TL;DR: In this paper, the authors describe the use of iron oxide nanoparticles in the fields of medicine, environmental area and analytical chemistry due to features such as a large special surface and simple separation with simple separation.
Abstract: Iron oxide nanoparticles have diverse applications in the fields of medicine, environmental area and analytical chemistry due to features such as a large special surface and simple separation with ...

Journal ArticleDOI
TL;DR: In this paper, a red nanofluorescent material based on Y2O2S: Eu3+ was prepared by the molten salt method, and multiple small-sized Y2 O2S sphere-shpaed particles ranging from 100nm to 200nm were prepared.
Abstract: Red nanofluorescent materials based on Y2O2S: Eu3+ were prepared by the molten salt method. Multiple small-sized Y2O2S sphere-shpaed particles ranging from 100 nm to 200 nm were prepared us...

Journal ArticleDOI
TL;DR: Palladium nanoparticles supported on EDTA-modified Fe3O4@SiO2 NPs as an efficient and magnetically reusable nanocatalyst was applied for the Heck cross-coupling reactions as mentioned in this paper.
Abstract: Palladium nanoparticles supported on EDTA-modified Fe3O4@SiO2 NPs as an efficient and magnetically reusable nanocatalyst was applied for the Heck cross-coupling reactions. The catalyst was ...

Journal ArticleDOI
TL;DR: Co(II) Schiff base complexes derived by condensation of 4-amino benzoic and 2-hydroxy-1-naphthaldehyde was immobilized into layered double hydroxide and characterized by vari...
Abstract: Co(II) Schiff base complexes derived by condensation of 4-amino benzoic and 2-hydroxy-1-naphthaldehyde was immobilized into layered double hydroxide, {LDH-[NAPABA-Co(II)]} and characterized by vari...

Journal ArticleDOI
TL;DR: In this article, the synthesis of aminocarbonyl derivatives as biologically active compounds by using polyethylene glycol (PEG-400)-SO3H-coated Fe2O3 is reported.
Abstract: The synthesis of aminocarbonyl derivatives as biologically active compounds by using polyethylene glycol (PEG-400)-SO3H-coated Fe2O3 is reported. The heterogeneous nanocatalyst was prepared via in-situ co-precipitation method and its structure and morphology was characterized by Fourier-transform infrared spectroscopy, energy-dispersive X-ray analysis, X-ray diffraction pattern, field-emission scanning electron microscopy image, vibrating sample magnetometer curves, N2 adsorption-desorption isotherm and inductively-coupled plasma analysis. Noteworthy, the green composite nanocatalyst was applied for the one-pot multicomponent synthesis of aminocarbonyl compounds at room temperature. This work had advantages such as significant nanocatalyst activity, recoverability, short process time, mild reaction conditions and high products yields.

Journal ArticleDOI
TL;DR: In this article, the nanoparticles were prepared via micro-emulsion procedure and reacted under H2O/1-butanol/isooctane/CTAB microemulsion.
Abstract: CuWO4 nanoparticles were prepared via microemulsion procedure. Cu(NO3)2 and Na2WO4 solutions were reacted under H2O/1-butanol/isooctane/CTAB microemulsion. The as-prepared material was calcined at ...

Journal ArticleDOI
TL;DR: In this paper, the authors reported a rapid green synthesis of silver nanoparticles using Skimmia laureola stem bark aqueous extract as reducing and stabilizing agent, when the bark extract was mixed with water.
Abstract: The present study reports a rapid green synthesis of silver nanoparticles using Skimmia laureola stem bark aqueous extract as reducing and stabilizing agent. When bark extract was mixed wit...

Journal ArticleDOI
TL;DR: In this article, the ligand complex of copper (II) supported on superparamagnetic Fe3O4@SiO2 nanoparticles was introduced as a highly intriguing magnetic catalyst in N-arylation of nitrogen heterocycle.
Abstract: In this study, we introduce the ligand complex of copper (II) supported on superparamagnetic Fe3O4@SiO2 nanoparticles as a highly intriguing magnetic catalyst in N-arylation of nitrogen heterocycle...

Journal ArticleDOI
TL;DR: In this article, the forced convective heat transfer for silver/water nanofluid in a shell and tube heat exchanger was investigated, and the results showed that the heat transfer was forced by the metal nanoparticles.
Abstract: This work reports an experimental investigation on the forced convective heat transfer for silver/water nanofluid in a shell and tube heat exchanger. At first, the silver nanoparticles were...

Journal ArticleDOI
TL;DR: In this paper, the artificial neural network and symbiotic organisms search (SOS) optimization algorithm were used for simulation and optimization of heavy metals removal from aqueous solutions by t...
Abstract: The artificial neural network (ANN) and symbiotic organisms search (SOS) optimization algorithm were used for simulation and optimization of heavy metals removal from aqueous solutions by t...

Journal ArticleDOI
TL;DR: It was concluded that the AgNP prepared from F. cretica extract were spherical and aggregated and were found effective against different clinical isolates of bacteria.
Abstract: Fagonia cretica L. is a known medicinal plant containing important biomolecules. The present study was designed to prepare the silver nanoparticles (AgNP) from F. cretica L. that has never ...

Journal ArticleDOI
TL;DR: In this article, a novel metal organic framework, namely, {[Zn3(btc)2(bimmb)2.5]·2H2O·CH3CN}n (1) (btc = 1,3,5-benzenetricarboxylic acid), bimmb = 1.4-bis(imidazol-l-ylmethyl) benzene), has been reasonably designed.
Abstract: A novel metal organic framework, namely, {[Zn3(btc)2(bimmb)2.5]·2H2O·CH3CN}n (1) (btc = 1,3,5-benzenetricarboxylic acid), bimmb = 1,4-bis(imidazol-l-ylmethyl) benzene), has been reasonably designed...

Journal ArticleDOI
TL;DR: In this article, the Fe-benzentricarboxylic (Fe-BTC) metal-organic framework was synthesized by sonochemistry in mixtures of solvents (DMF: H2O: Ethanol) with different volume ratios.
Abstract: In this study, the Fe-benzentricarboxylic (Fe-BTC) metal-organic framework was synthesized by sonochemistry in mixtures of solvents (DMF: H2O: Ethanol) with different volume ratios. The performance...

Journal ArticleDOI
TL;DR: Results suggest that the FeNPs may be considered as eco-friendly compound for the control of mosquitoes and harmful microorganisms.
Abstract: Disease-causing microbes that have become resistant to drug therapy and resistant strains of mosquito vectors pose serious public health problems. Therefore, there is need to develop bio-origin ant...