Showing papers in "Journal of Environmental Engineering in 2008"

Pollutant Removal and Peak Flow Mitigation by a Bioretention Cell in Urban Charlotte, N.C.

Abstract: Bioretention is a stormwater treatment practice that has gained popularity due to its aesthetics, potential to reduce flooding, and early documented improvements to stormwater quality. A bioretention cell in an urban setting was examined in Charlotte, N.C. from 2004 to 2006. Flow-weighted, composite water quality samples were collected for 23 events and analyzed for TKN, N H4 -N , N O2-3 -N , TP, TSS, BOD-5, Cu, Zn, Fe, and Pb. Grab samples were collected from 19 storms for fecal coliform and 14 events for Escherichia coli (E. coli). There were significant reductions (p<0.05) in the concentrations of TN, TKN, N H4 -N , BOD-5, fecal coliform, E. Coli, TSS, Cu, Zn, and Pb. Iron concentrations significantly increased (p<0.05) . N O2-3 -N concentrations were essentially unchanged. Efficiency ratios for TN, TKN, N H4 -N , TP, and TSS were 0.32, 0.44, 0.73, 0.31, and 0.60, respectively. Fecal coliform and E. coli efficiency ratios were 0.69 and 0.71, respectively. Efficiency ratios for Zn, Cu, and Pb were 0.77,...

Urban Particle Capture in Bioretention Media. I: Laboratory and Field Studies

Abstract: Bioretention is a novel stormwater best-management practice that uses a mixture of soil/sand/mulch as adsorptive filtration media that can capture both urban particulates and dissolved pollutants while promoting infiltration. This study conducted a series of laboratory column experiments and field observations, which showed that: (1) bioretention media stratification occurs with runoff percolation due to particulate deposition; (2) bioretention filter media are clogging limited, instead of breakthrough limited; and (3) both depth filtration and cake filtration significantly contribute to urban particle capture. Because of the fine size of bioretention media, incoming suspended solids cannot significantly penetrate below 5–10 cm of the media in the column tests and approximately 20 cm in the monitored field facility. Bioretention filters under intermittent flow conditions exhibited higher solids loading capacity (in kg∕ m2 ) before clogging than under continuous flow conditions. The clay components in inco...

Optimizing Struvite Production for Phosphate Recovery in WWTP

Abstract: Struvite, a crystalline structure comprised of ions of magnesium Mg +2 , ammonium NH4 -N , and phosphate PO4 -P ,i s commonly encountered in wastewater treatment plants WWTPs through struvite encrustation. The gradual accumulation of this crystal in pipes and fittings leads to high costs due to downtime and replacement of parts. Technologies that are used to reduce this problem are ideally located in biological nutrient removal plants downstream of anaerobic digesters, as high levels of NH4 - N and PO4 - P typically characterize anaerobic digester supernatants. In 2003-2004, two technical-scale, struvite recovery studies were conducted on-site at the City of Penticton, B.C., Canada and the City of Richmond, B.C., Canada using a novel technology developed by the environmental engineering group at the University of British Columbia. The results of these studies showed an average reduction of 80% in phosphate and a dense, spherical product, 5-10 times larger than any commercially available struvite to date. Overall, the recovery of struvite has enormous commercial potential, which results in WWTP becoming more sustainable, concurrently reducing problems typically associated with their operation.

Performance Assessment of Hydraulic Efficiency Indexes

Abstract: The analysis of residence time distribution functions originating from tracer studies is one of the main tools for the assessment of hydraulic performance in water and wastewater treatment units. In order to simplify the analysis, hydraulic indexes extracted from these functions are normally used. In general, these indexes are divided into two categories: short circuit and mixing indicators. However, some indexes may be related to more than one physical phenomenon (i.e., short circuit, mixing, recirculation, dead zones), leading to erroneous interpretation. In this work their capability to evaluate short-circuit and mixing levels in water and wastewater treatment units is assessed. Among the indexes analyzed, t10 , which is the time necessary for 10% of the tracer to leave the unit, is recommended as a short-circuit indicator and the dispersion index ( σ2 ) and the Morril index as mixing indicators, depending on the mixing level.

Evaluating the Effectiveness of Best Management Practices Using Dynamic Modeling

Abstract: Structural best management practices (BMPs) have become a tool for stormwater managers to achieve water quality improvement and regulatory compliance. Existing empirical evaluation of BMP performance is valuable, but has limited applicability to predict BMP performance over extended durations under a variety of storm types. This study applies a dynamic model to simulate BMP performance over a 10-year period. The BMP model used hourly output from a calibrated and validated land-use model to evaluate two BMP types: a retention facility and a flow-through swale. The model evaluated each BMP alone and in series targeting volume, total suspend solids, and total copper. Effectiveness was based on load reduction, event mean concentrations, and frequency of exceedence of relevant water quality standards. The model predicted over 60% removal of solids and copper over most conditions; however, effectiveness was reduced during large storms and wet years. Although performance was similar based on load reduction and water quality standard exceedence, the latter was most sensitive to storm size. This study demonstrates that BMP modeling can help managers understand expected BMP performance over a range of storms, time periods, and design parameters, and, perhaps more significantly, evaluate BMPs in series.

Making asset investment decisions for wastewater systems that include sustainability

Abstract: Effective integrated water management is a key component of the World Water Vision and the way in which aspirations for water equity may be realized. Part of the vision includes the promotion of sustainability of water systems and full accountability for their interaction with other urban systems. One major problem is that “sustainability” remains an elusive concept, although those involved with the provision of urban wastewater systems now recognize that decisions involving asset investment should use the “triple bottom line” approach to society, the economy, and the environment. The Sustainable Water Industry Asset Resource Decisions project has devised a flexible and adaptable framework of decision support processes that can be used to include the principles of sustainability more effectively. Decision mapping conducted at the outset of the project has shown that only a narrow range of criteria currently influence the outcome of asset investment decisions. This paper addresses the concepts of sustainab...

Urban Particle Capture in Bioretention Media. II: Theory and Model Development

Abstract: As a novel stormwater best-management practice, using a soil/sand/mulch mixture to capture urban pollutants while promoting infiltration, the unique media composition renders bioretention significantly different from conventional sand filters. In this work, a three-layer model is presented to describe particulate capture in bioretention media employing parameter calibration and presensitivity analysis. Since the fine size of bioretention media strictly limits the particulate penetration distance, the media column is modeled as a pristine zone (bottom), a working zone (middle), and a cake zone (top). Mechanisms of both depth filtration and cake filtration are examined through mass balances, which show that both are significant. The developed resistance of each layer due to solid deposition was also estimated. Experimental data for different media/TSS-type combinations of selected experimental trials were used in parameter calibration. The calibrated model successfully predicted the effluent TSS and media hydraulic conductivity of subsequent trials with appropriate boundary and initial conditions as input. A weighted combination of calibrated parameters from different TSS types also agreed well with media behavior for treating a complex TSS mixture. The results of media replacement (top removal and refill) simulation also reasonably fit experimental data. Using proper assumptions, a long-term scenario analysis for permeability reduction was performed for a field bioretention facility. Based on modeling results, this study recommends a shallow bioretention media depth design, an annual or biannual field inspection schedule, and periodic media replacement maintenance.

Comparison of Steroid Hormone Concentrations in Domestic and Hospital Wastewater Treatment Plants

Abstract: Influent and effluent samples originating from two wastewater treatment plants (WWTPs) (treating hospital wastewater and domestic wastewater, Belgium) have been analyzed in order to estimate their steroid hormone content. The natural estrogens estrone (E1), 17β -estradiol (E2), and the synthetic 17α -ethinylestradiol (EE2) together with other steroid hormones progesterone (P) and testosterone (T) metabolites were detected in these samples. The hormone concentrations in both the hospital and the domestic WWTP samples were not significantly different and ranged from 100 ng P/L. E2 was detected once at a concentration of 17 ng∕L . In the domestic WWTP which comprises a conventional activated sludge treatment in parallel with a membrane bioreactor, no differences in estrogen removal efficiency could be observed for both treatments. In comparison to chemical analysis data, the Yeast Estrogen Screen (YES) appears to underest...

Metal Stimulation and Municipal Digester Thermophilic/Mesophilic Activity

Abstract: Biomass from thermophilic and mesophilic digesters (four temperature-phased anaerobic digesters and one phased thermophilic digester) was assayed for potential methane production rate increases resulting from nutrient (Ni, Co, and Fe) addition. Furthermore, digester operations and biomass activities were compared. The majority (77%) of biomass samples benefited from nutrients, with propionate and acetate utilization rates increasing as much as 50 and 35%, respectively, after nutrient addition. Propionate utilization rates were more frequently stimulated by nutrient addition, demonstrating increased methane production rates of from 14 to 50% upon nutrient amendment. Others have observed difficulty achieving low propionate concentrations in municipal thermophilic digesters, especially at lower retention times. Trace nutrient supplementation is one method to increase propionate and acetate utilization in some municipal thermophilic as well as mesophilic digesters.

Documenting Stormwater Quality on Texas Highways and Adjacent Vegetated Roadsides

Abstract: The primary objective of this study is the documentation of stormwater quality of vegetated roadsides of two Texas highways (State Highway 6 in College Station and Loop 360 in Austin), both of which had high average daily traffic. Three sites each in Austin and College Station were monitored using passive “first flush” stormwater samplers for 16 months. Results from this study indicate that significant removal of sediment and heavy metals occurred over the width of vegetated roadsides, but no apparent nutrient (nitrogen and phosphorus) removal was observed. The results also show that vegetation density has a direct effect on the performance of vegetated roadsides. When roadsides are densely covered with grasses above 90%, significant sediment removal is expected, often within the first 4 m of the edge of pavement. A stepwise regression analysis identifies the antecedent dry period (ADP) as the most significant predictor to pollutant concentration. The pollutant event mean concentration was found to decrease with increasing ADP for all pollutants at the College Station sites, but not the Austin ones.

Air Injection in Water with Different Nozzles

Abstract: Air injection systems have a wide range of environmental engineering applications. In this study, we conducted experiments on air injection in a relatively large water tank to investigate the effect of nozzle type, including single/multiple orifice nozzles and a porous airstone, on the characteristics of the bubbles and the induced flow structure. Measurements of bubble characteristics and flow field surrounding the bubble core were obtained using a double-tip optical probe and particle image velocimetry, respectively. The results revealed that bubble velocity did not change significantly with different nozzles, but bubble size decreased significantly while interfacial area, liquid entrainment rate, and kinetic energy of the mean and turbulent flow increased significantly by using the porous airstone instead of nozzles with large orifices. The results for a nozzle with multiple orifices of small diameter are comparable to those for the airstone, which suggests the suitability of its use for systems susceptible to clogging of the pores. Correlations using adequate length and velocity scales are also proposed to describe both bubble and liquid flow characteristics. Finally, applications of the results for different artificial aeration/mixing systems are presented.

Ozone Degradation of Iodinated Pharmaceutical Compounds

Abstract: This study investigates the aqueous degradation of four iodinated x-ray contrast media (ICM) compounds (diatrizoate, iomeprol, iopromide, and iopamidol) by ozone and combined ozone and hydrogen peroxide. In laboratory scale experiments, second-order kinetic rate constants for the reactions of the ICM compounds with molecular ozone and hydroxyl radicals, and overall at pH 7.5, were determined. For the four ICM compounds the degradation rate constants with molecular ozone were low and in the range of 1–20 M−1 s−1 , whereas the rate constants with hydroxyl radicals were in the range of 1× 109 –3× 109 M−1 s−1 . Diatrizoate had the lowest rate constant of the four compounds with respect to molecular ozone reactions. At pH 7.5, the extent of compound degradation was proportional to the applied ozone dose and inversely related to the initial compound concentration at a given ozone dose. At this pH approximately 90% of the degradation could be attributed to hydroxyl radical reactions. Enhancement of the radical m...

Utility of Suspended Solid Measurements for Storm-Water Runoff Treatment

Abstract: In this paper alternative solutions are presented to solve problems associated with the measurement of total suspended solids (TSS) in storm-water runoff. Results revealed that the accuracy of TSS measurement is largely related to sample representativeness, particle size distribution (PSD), sampling pipette position, and sample mixing. In general, when the PSD in the runoff was mostly larger than 75 μm , the most accurate and reproducible results were obtained when samples were collected from a position of mid-depth and midway between the walls of the beaker and the vortex and mixed at speeds in the range of 600–700 rpm . For runoff samples with a PSD smaller than 75 μm , mixing at a higher rpm is not a significant factor. As long as the PSD in the TSS subsample is representative of the original sample, a strong correlation between TSS and suspended solid concentration can be achieved. The results showed that density was largely correlated with the organic content of the particles, and, in general, smalle...

Spatial-Dynamic Modeling of Algal Biomass in Lake Erie: Relative Impacts of Dreissenid Mussels and Nutrient Loads

Abstract: Over the past several decades, reductions in phytoplankton stocks and increased water clarity in Lake Erie have resulted from phosphorus load abatement and the introduction of zebra Dreissena polymorpha and quagga mussels D. bugensis. The relative impacts of these developments and their implications for lake management have remained difficult to delineate. To address this issue, we numerically model the complex biophysical interactions occurring in Lake Erie using a two-dimensional hydrodynamic and water quality model that is extended to include dreissenid mussel and zooplankton algorithms. The model reasonably simulates longitudinal trends in water quality as well as the dynamics of central basin hypoxia. Phosphorus is the limiting nutrient through the euphotic zone and its control decreases the algal growth rate and biomass 55-60%. Filter feeding by dreissenid mussels also decreases algal biomass 25-30%, simultaneously stimulating increased net algae growth through enhanced algal consumption and subsequent phosphorus recycling. Effective recycling implies that algae stocks are ultimately regulated by external phosphorus loads. Returning phosphorus loads to pre-abatement 1960s levels, in the presence of dreissenid mussels, results in a western basin algae concentration of 0.7 mg dry weight L 1 with a potential for nuisance algae growth.

Chemical Oxygen Demand and the Mechanism of Excess Sludge Reduction in an Oxic-Settling-Anaerobic Activated Sludge Process

Abstract: A modified activated sludge process, called the oxic-settling-anaerobic (OSA) process, achieved effective reduction in excess sludge production. Its key feature is the insertion of a sludge holding tank in the sludge return circuit to provide an anaerobic sludge zone. Our previous studies suggested that such excess sludge reduction might be associated with an increased sludge decay rate and the effective consumption of organic substrates generated during the retention of the thickened sludge in the sludge holding tank under a low oxidation-reduction potential (ORP) at −250 mV . To confirm this suggestion, we analyzed the chemical oxygen demand (COD) balance in the sludge holding tank through batch experiments to simulate the sludge concentration, ORP level, and retention time in the sludge holding tank. The COD generated from the sludge reduction in the tank was utilized by organic gas (mainly CH4 ) production, denitrification, sulfate reduction, and phosphorus release, among which the gas production acco...

Controlled Field Experiment for Performance Evaluation of Septic Tank Effluent Treatment during Soil Infiltration

Abstract: Decentralized systems are responsible for treating approximately 25% of the wastewater generated in the United States. The most common decentralized system involves onsite treatment using a septic tank unit followed by dispersal to a subsurface soil infiltration unit where percolation to groundwater occurs. To evaluate the hydraulic and purification processes occurring during soil treatment of septic tank effluent (STE), a field experiment was initiated in the Spring of 2003 with continued operation and monitoring for 2 years. A replicated factorial design ( 22 ) was employed to evaluate three infiltrative surface architectures (ISAs) (open, stone, and synthetic) and two daily hydraulic loading rates (HLRs) (4 and 8 cm∕day ). Pilot-scale test cells were established in native sandy loam soils at the Mines Park Test Site located on the Colorado School of Mines campus in Golden, Colo. STE was obtained from a nearby multifamily apartment building and applied to the test cells daily. Field monitoring included ...

Real — Time Speciation of Uranium during Active Bioremediation and U(IV) Reoxidation

Abstract: The biological reduction of uranium from soluble U(VI) to insoluble U(IV) has shown potential to prevent uranium migration in groundwater. To gain insight into the extent of uranium reduction that can occur during biostimulation and to what degree U(IV) reoxidation will occur under field relevant conditions after biostimulation is terminated, X-ray absorption near edge structure (XANES) spectroscopy was used to monitor: (1) uranium speciation in situ in a flowing column while active reduction was occurring; and (2) in situ postbiostimulation uranium stability and speciation when exposed to incoming oxic water. Results show that after 70 days of bioreduction in a high (30 mM) bicarbonate solution, the majority (>90%) of the uranium in the column was immobilized as U(IV). After acetate addition was terminated and oxic water entered the column, in situ real-time XANES analysis showed that U(IV) reoxidation to U(VI) (and subsequent remobilization) occurred rapidly (on the order of minutes) within the reach of the oxygen front and the spatial and temporal XANES spectra captured during reoxidation allowed for real-time uranium reoxidation rates to be calculated.

Selection of Suitable Aggregation Function for Estimation of Aggregate Pollution Index for River Ganges in India

Abstract: The present study aims to select the most appropriate aggregation function for estimation of the Ganga River pollution index (GRPI). Following the Delphi technique based on expert opinion, 16 water pollutant variables are selected; the weights of each pollutant variable based on their relative significance are determined, and the average subindex curves for each variable are drawn. Using the weights, average parameter’s value and the corresponding subindex value, 18 different aggregation functions are tested and analyzed. Literature reveals that most aggregation methods suffer from ambiguity and eclipsing problems due to faulty selection of aggregation function. From the results of the present analysis, 12 aggregation functions are screened out on the basis of ambiguity and eclipsing, constant functional behavior, and nonaccountability of weights in functions criteria. Finally, the remaining 6 aggregation functions are subjected to sensitivity analysis. From the results of sensitivity analysis, it is conc...

Fuzzy Inexact Mixed-Integer Semiinfinite Programming for Municipal Solid Waste Management Planning

Abstract: Based on the concept of functional intervals, fuzzy inexact mixed-integer semiinfinite programming (FIMISIP) method is developed for municipal solid waste management planning. The method allows the uncertainties in parameters expressed as fuzzy, interval, and functional interval numbers to be directly communicated into the programming problem. The FIMISIP problem is solved by dividing it into two interactive semiinfinite programming (SIP) subproblems. Solutions reflecting the inherent uncertainties can then be generated by combining the SIP solutions into a set of decision intervals. The method is applied to a municipal solid waste management planning system for demonstrating its effectiveness in dealing with uncertain and dynamic complexities. Compared to the previous inexact programming methods, FIMISIP has the advantages as follows: (1) the dynamic complexity can be addressed by introducing the functional-interval parameters associated with time into the programming problem; (2) the FIMISIP solutions p...

Comparison of Computation Fluid Dynamics Simulation against Tracer Data from a Scale Model and Full-Sized Waste Stabilization Pond

Abstract: The use of computation fluid dynamics (CFD) for waste stabilization pond design is becoming increasingly common but there is a large gap in the literature with regard to validating CFD pond models against experimental flow data. This paper assesses a CFD model against tracer studies undertaken on a full-sized field pond and then on a 1:5 scale model of the same pond operated under controlled conditions in the laboratory. While the CFD tracer simulation had some discrepancies with the field data, comparison to the laboratory model data was excellent. The issue is, therefore, not in the way the model solves the problem, for example, the choice of turbulence model or differencing scheme, but rather with how accurately the physical conditions in the field are defined. Extensive survey of the sludge layer and transient input of changing flow rates, wind velocities, and temperature could allow closer alignment of CFD simulations to field data. However, in the practical application of CFD where a modification such as baffle installation results in a large change, then a simple pragmatic model, while not exact, can still provide valuable design insight.

Artificial Intelligence-Based Inductive Models for Prediction and Classification of Fecal Coliform in Surface Waters

Abstract: This paper describes the use of inductive models developed using two artificial intelligence (AI)-based techniques for fecal coliform prediction and classification in surface waters. The two AI techniques used include artificial neural networks (ANNs) and a fixed functional set genetic algorithm (FFSGA) approach for function approximation. While ANNs have previously been used successfully for modeling water quality constituents, FFSGA is a relatively new technique of inductive model development. This paper will evaluate the efficacy of this technique for modeling indicator organism concentrations. In scenarios where process-based models cannot be developed and/or are not feasible, efficient and effective inductive models may be more suitable to provide quick and reasonably accurate predictions of indicator organism concentrations and associated water quality violations. The relative performance of AI-based inductive models is compared with conventional regression models. When raw data are used in the development of the inductive models described in this paper, the AI models slightly outperform the traditional regression models. However, when log transformed data are used, all inductive models show comparable performance. While the work validates the strength of simple regression models, it also validated FFSGA to be an effective technique that competes well with other state-of-the-art and complex techniques such as ANNs. FFSGA comes with the added advantage of resulting in a simple, easy to use, and compact functional form of the model sought. This work adds to the limited amount of research on the use of data-driven modeling methods for indicator organisms.

Optimization of Settling Tank Design to Remove Particles and Metals

Abstract: Mass reduction rates of particles and metals were simulated for a two-compartment settling tank composed of a storage compartment and a continuous flow compartment. Particle-size distribution, rainfall, and flow data from 16 storm events measured at three highway sites were used. The volume ratio (i.e., ratio of surface areas for a given depth) between storage and continuous flow compartment was optimized for a given design storm size to maximize total mass reduction rates of particles and heavy metals. Measured settling velocity profiles of runoff samples were used in the simulation. Simulation results showed that in a given total design storm, larger storage compartment fractions (>0.95) enhanced the removal of smaller particles (2–104 μm) and particulate phase metals, and even a small fraction (<0.05) of continuous flow compartment effectively removed larger particles (104–1,000 μm) . A volume fraction of 0.75 for the storage compartment is suggested to optimize annual reductions of particles and assoc...

Estimation of the Maximum Consumption of Permanganate by Aquifer Solids Using a Modified Chemical Oxygen Demand Test

Abstract: Knowledge of the consumption of permanganate by naturally occurring reduced species associated with aquifer materials is required for site screening and design purposes to support permanganate in situ chemical oxidation (ISCO) applications. It has been established that this consumption is not a singled-valued quantity, but rather is kinetically controlled. Current methods to determine this permanganate natural oxidant demand (NOD) involve the use of well-mixed batch tests, which are time consuming and subject to test variables (e.g., concentration, mass of oxidant to solid ratio, reaction duration, and mixing conditions) that significantly affect the results. In this paper, we propose a modified chemical oxygen demand (COD) test using permanganate, which can be used to determine the maximum permanganate NOD of an aquifer material. As an initial point of comparison, we tested aquifer materials collected from eight potential ISCO sites using this modified or permanganate COD method, the traditional dichroma...

Evaluation of Chemical Treatments for a Mixed Contaminant Soil

Abstract: Treatability tests were conducted on soil from the reservoir No. 2 burning ground at the former Plum Brook Ordnance Works in Sandusky, Ohio. This soil is contaminated with explosives 2,4,6-trinitrotolune (TNT) and 2,4/2,6-dinitrotoluene (DNT), polychlorinated biphenyls (PCB, Aroclor 1260), as well as lead. Lime treatment (alkaline hydrolysis) and persulfate oxidation were tested individually and in combination to treat explosives and PCBs. Lime treatment removed 98% of TNT, 75% of DNT, and 80% of PCBs. Similar removal levels were found for persulfate treatment as well as lime followed by persulfate. The percentage of contaminant removal was found to be independent of initial contaminant concentrations. Treatments of the most contaminated soil did not meet the preliminary remediation goals for explosives or PCBs but would allow for disposal in a nonhazardous waste landfill. Treatment of soil with lower initial concentrations easily met the residential (most stringent) preliminary remediation goals of 16, 6...

Impact of Initial pH and Linoleic Acid (C18:2) on Hydrogen Production by a Mesophilic Anaerobic Mixed Culture

Abstract: Hydrogen production from glucose using a mixed anaerobic culture was assessed under batch conditions by adjusting the initial pH and adding linoleic acid (LA). At an initial pH of 5.0, hydrogen ( 1.9 mol H2 mol−1 glucose) was detected after the first glucose injection in the controls (no LA added). At the latter initial pH and in cultures fed 2,000 mg l−1 LA, the yield reached a maximum of 2.4 mol H2 mol−1 glucose when glucose was injected again. Hydrogen was detected after the second glucose injection in cultures with the initial pH adjusted to 5.0 and 6.0. In cultures receiving LA and adjusted to pH 7.6, the hydrogen yield reached 1.4 mol H2 mol−1 glucose when glucose was injected again. Acetate, propionate, and butyrate were detected under all conditions; however, the quantities were variable and dependent on the conditions examined. In comparison to the amount of volatile fatty acids produced, relatively low quantities of alcohols (ethanol, i-propanol, n-butanol, and i-butanol) were detected during th...

Examination on Process Configurations Incorporating Thermal Treatment for Anaerobic Digestion of Sewage Sludge

Abstract: This study aimed to examine the process configurations for mesophilic anaerobic digestion of sewage sludge, when incorporated with thermal treatment of 120°C for 1 h. Four types of process configurations were designed: control (no thermal treatment), pretreatment and posttreatment configurations of the single-stage process, and an interstage-treatment configuration of the two-stage process. The lab-scale digesters were operated at 35°C with the sewage sludge of 4.5% total solids, and were equally set at the total hydraulic retention time of 20 days. At the steady state, the control digester showed 35.3% of volatile solids (VS) destruction and 0.168 L/g VS fed of methane production. Compared to the control, the VS destruction in the pre-, post-, and interstage-treatment configurations was increased by 4.5, 6.6, and 9.9%, respectively, while the methane production in the post- and interstage-treatment configurations was improved by 0.036 and 0.028 L/g VS fed, respectively. The pretreatment configuration yielded identical methane production to the control. Therefore, it is more effective on anaerobic digestibility to apply the moderate thermal treatment after sewage sludge is digested once. On the other hand, the increase in soluble chemical oxygen demand and deterioration of dewaterability were observed, when solids destruction was improved.

Estimation of Engine Emissions from Commercial Aircraft at a Midsized Turkish Airport

Abstract: The estimated atmospheric emissions of aircraft operations at a midsized Turkish airport (Adnan Menderes Airport, AMA) for the year 2004 are presented in this paper. The landing and takeoff (LTO) emissions of hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (N OX ) were calculated using the flight data recorded by the State Airports Authority Directorate General. Emission factors from the International Civil Aviation Organization Engine Exhaust Emission Databank were used for different aircraft operation modes such as take-off, climbout, approach, and taxi/idle engine conditions. Total LTO emissions from commercial aircrafts at AMA were estimated as 21 t∕y for HC, 138 t∕y for CO, and 197 t∕y for N OX . Boeing 737-800 type aircrafts have the biggest portions in total emissions (12% for HC, 18% for CO, and 35% for N OX ). It is estimated that an increase of 1 min in taxiing time causes an increase of 4.2%, 4.6%, and 0.4% in the amount of HC, CO, and N OX emissions, respectively. Estimations show...

Using CFD Modeling to Improve the Inlet Hydraulics and Performance of a Storm-Water Clarifier

Abstract: The feasibility of high-rate treatment of storm water achieving total suspended solids (TSS) removals in the range from 60 to 80% was studied using an available clarifier. The clarifier ( 3 m long, 1.4 m wide, and 2 m deep) was fitted with a removable lamella pack and had a limited flow capacity (surface load rate of 35 m∕h ). To achieve the desired removals of TSS, the clarifier required polymer feed (4 mg∕L) , which caused maintenance problems during intermittent storm-water treatment—laborious and costly cleaning of lamella plates after individual storm events. This problem posed the following challenge: was it feasible to avoid costly maintenance by removing the lamella pack and at the same time to retain the high TSS removals by improving the clarifier hydraulics by internal structural changes? The purpose of the paper is to evaluate such changes by focusing on different inlet configurations designed using computational fluid dynamics (CFD) simulations. This analysis resulted in adopting a U-tube duc...

pH and Acid Anion Time Trends in Different Elevation Ranges in the Great Smoky Mountains National Park

Abstract: Quarterly base flow water quality data collected from October, 1993 to November, 2002 at 90 stream sites in the Great Smoky Mountains National Park were used in step-wise multiple linear regression models to analyze pH, acid neutralizing capacity (ANC), and sulfate and nitrate long-term time trends. The potential predictor variables included cumulative Julian day, seasonality, elevation, basin slope, stream order, precipitation, surrogate streamflows, geology, and acid depositional fluxes. Modeling revealed statistically significant decreasing trends in pH and sulfate with time at lower elevations, but generally no long-term time trends in stream nitrate or ANC. The best forecasting models were chosen based on maximizing the r2 of a holdout data set. If conditions remain the same and past trends continue, the forecasting models suggest that 30.0% of the sampling sites will reach pH values less than 6.0 in less than 10 years , 63.3% in less than 25 years , and 96.7% in less than 50 years . The pH forecasti...

Hydrodynamic Characteristics in Biotrickling Filters as Affected by Packing Material and Hydraulic Loading Rate

Abstract: Hydrodynamics in biotrickling filters can be strongly influenced by packing material geometry and hydraulic loading rate. While it is generally accepted that increasing wetted area in a biotrickling filter can improve process performance, additional research on synthetic packing materials and parameters that improve hydrodynamics, resulting in increased wetted area, is desirable. For this research, a series of tracer tests was conducted to compare hydrodynamics in bench scale biotrickling filters with three different packing materials under three different flow rates. Results suggest that of the three packing materials, the material with the highest specific surface area resulted in channeling and excessive formation of stagnant zones within the biotrickling filters. Liquid distribution through the biotrickling filters substantially improved at a hydraulic loading rate of 1.9 m∕hr for all packing materials, but based on these experiments, improvements were minimal when the hydraulic loading rate was incre...