Journal ArticleDOI
3-and 4-cyanopyridine complexes of pentacyanoferrate(II) and pentacyanocobaltate(III)
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TLDR
In this article, the preparation and properties of 3-and 4-cyanopyridine complexes with the Fe(CN) 3−5 and Co(CN 2−5 groups are described.About:
This article is published in Inorganica Chimica Acta.The article was published on 1979-01-01. It has received 22 citations till now. The article focuses on the topics: Pyridine & NMR spectra database.read more
Citations
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Three redox states of nitrosyl: NO+, NO*, and NO-/HNO interconvert reversibly on the same pentacyanoferrate(II) platform.
Andrea C. Montenegro,Valentín T. Amorebieta,Leonardo D. Slep,Diego F. Martín,Federico Roncaroli,Daniel H. Murgida,Sara E. Bari,José A. Olabe +7 more
TL;DR: [Fe(II)(CN)(5)(HNO)](3-) is the first non-heme iron-nitroxyl complex prepared in aqueous solution that is reversibly redox-active under biologically relevant conditions.
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Mono and dinuclear iridium, rhodium and ruthenium complexes containing chelating carboxylato pyrazine ligands: Synthesis, molecular structure and electrochemistry
TL;DR: In this article, the pyrazine-2,5-dicarboxylato unit bridges two metal centers and the electrochemical behavior of selected representatives has been studied by voltammetric techniques.
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Synthesis and spectroscopic properties of cationic Ru(II) arene complexes [Ru(η6-arene)(P)Cl(L)]+. (P=PPh3, PEt3, MePPri2 and L=4-cyanopyridine or 1,4-dicyanobenzene)
TL;DR: In this article, a pendant nitrile group was detected in the reaction products of [Ru(η6-arene)(P)Cl2] with organonitriles 4-cyanopyridine or 1,4-dicyanobenzene (referred hereafter as CNPy or DCB) in methanol.
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Solvent and pressure effects on kinetics of substitution at pentacyanoferrate(II) anions
TL;DR: In this article, rate constants for substitution at the pentacyanoferrate(II) anions Fe(CN)5L3−, for L=4-cyanopyridine and 2-methylpyrazine, as a function of temperature at atmospheric pressure in methanol-water mixtures and at 298.2 K in aqueous solution.
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Syntheses and characterization of η5-cyclopentadienyl and η5-indenyl ruthenium(II) complexes of arylazoimidazoles: The molecular structure of the complex [(η5-C5H5)Ru(PPh3)(C6H5–NN–C3H3N2)]+
TL;DR: In this article, the molecular structure of the complex (η5-C5H5)Ru(PPh3)2Cl was established by single crystal X-ray diffraction study.
References
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Journal ArticleDOI
Properties and reactivity of some pentacyanoferrate(II) complexes of aromatic nitrogen heterocycles
Henrique E. Toma,John M. Malin +1 more
Journal ArticleDOI
Benzonitrile and acetonitrile complexes of ruthenium ammines
Richard E. Clarke,Peter C. Ford +1 more
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Reactions of ferropentacyanamines
TL;DR: A series of compounds of the general type, Na3Fe(CN)5NR3, were prepared and their reactions under an atmosphere of N2, O2, and CO were studied.
Related Papers (5)
Kinetics of formation and dissociation of complexes of pentacyanoferrate(II) with benzonitrile, dicyanobenzenes and cyanopyridines
Properties and reactivity of some pentacyanoferrate(II) complexes of aromatic nitrogen heterocycles
Henrique E. Toma,John M. Malin +1 more