4-{[1-(4-Bromophenyl)ethyl]aminomethyl}phenol
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TLDR
The title compound, C15H16BrNO, obtained from a two-step reaction, was prepared for use in transition metal chemistry as a phenolic ligand with bulky substituents as mentioned in this paper.Abstract:
The title compound, C15H16BrNO, obtained from a two-step reaction, was prepared for use in transition metal chemistry as a phenolic ligand with bulky substituents. Intermolecular N—H⋯O and O—H⋯N hydrogen bonds are present in the crystal structure.read more
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A short history of SHELX
TL;DR: This paper could serve as a general literature citation when one or more of the open-source SH ELX programs (and the Bruker AXS version SHELXTL) are employed in the course of a crystal-structure determination.
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Chiral transition metal clusters from two enantiomeric schiff base ligands. Synthesis, structures, CD spectra and magnetic properties
Linlin Fan,Fu-Sheng Guo,Lei Yun,Zhuo-Jia Lin,Radovan Herchel,Ji-Dong Leng,Yong-Cong Ou,Ming-Liang Tong +7 more
TL;DR: Two enantiomeric Schiff base ligands R-/S-H2L in situ generated from the condensation of o-vanillin with R- or S-2-phenylglycinol were applied to assemble chiral multinuclear transition metal magnetic clusters for the first time.
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Octahedral copper(II) and tetrahedral copper(I) double-strand helicates: chiral self-recognition and redox behavior.
TL;DR: Single crystal X-ray diffraction studies have shown that the Cu(II) complex exists as double-strand homochiral helicate molecules: P,P-[Cu(2)(II)((RR)5)(2)](4+) and M,M-[Cu (2)( II)((SS)5)*(4+); in which the two trans-1,2-cyclohexanediamine subunits have the same chirality for of the two strands