Journal ArticleDOI
412. Studies in the sterol–oestrone group. Part I. A synthesis of 3′-keto-3 : 4-dihydro-1 : 2-cyclopentenophenanthrene.
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This article is published in Journal of The Chemical Society (resumed).The article was published on 1936-01-01. It has received 13 citations till now. The article focuses on the topics: Sterol.read more
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The bacterial oxidation of aromatic compounds.
TL;DR: Adaptive patterns for a vibrio indicate that the oxidation of phenylalanine to homogentisic acid by this organism may proceed by two different pathways, one through phenylpyruvic and phenylacetic acids and the other through tyrosine and p-hydroxyphenyl pyruvic acid.
Journal ArticleDOI
The bacterial oxidation of aromatic compounds; III. The enzymatic oxidation of catechol and protocatechuic acid to beta-ketoadipic acid.
TL;DR: Investigations reported in the present paper show that both aromatic compounds are converted quantitatively by dried cells into ,B-ketoadipic acid, thus confirming in a direct manner Kilby's inference that this aliphatic acid is an intermediate in the oxidations of aromatic compounds.
Journal ArticleDOI
Regulation of aromatic metabolism in the fungi: metabolic control of the 3-oxoadipate pathway in the yeast Rhodotorula mucilaginosa.
K. A. Cook,R. B. Cain +1 more
TL;DR: Evidence is presented which suggests that R. mucilaginosa is unable to metabolize catechol or its usual precursors, and the significance of this is discussed in relation to control of the protocatechuate branch and the differing control mechanisms governing the synthesis of enzymes of the 3-oxoadipate pathway in other fungi and bacteria.
Journal ArticleDOI
A new synthesis of diethyl β-ketoadipate
Edward C. Taylor,A. McKillop +1 more
TL;DR: In this paper, a new and reliable synthesis of diethyl β-ketoadipate (Ia) is described, in which the ethoxymagnesio derivative of ethyl t-butyl malonate is condensed with β-carbethoxypropionyl chloride to the triester (VI, R = Et), which is decomposed by refluxing under vacuum in the presence of added acid.