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A four-shell, nesting doll-like 3d-4f cluster containing 108 metal ions.

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This article is published in Angewandte Chemie.The article was published on 2008-03-14. It has received 211 citations till now.

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Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes

TL;DR: In this paper, a review of 3d-4f heterometallic discrete complexes is presented, focusing on the examples showing dynamics of the magnetization, as well as the synthetic strategy, structures and magnetic properties.
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High-Nuclearity 3d–4f Clusters as Enhanced Magnetic Coolers and Molecular Magnets

TL;DR: Four 52-metal-ion 3d-4f cluster complexes featuring a common core of Ln(42)M(10) were obtained through self-assembly of the metal ions templated by mixed anions (ClO(4)(-) and CO(3)(2-)).
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Magnetic lanthanide–transition-metal organic–inorganic hybrid materials: From discrete clusters to extended frameworks

TL;DR: In this paper, the structures and magnetic properties of lanthanide transition-metal hybrid materials are classified based on the structural features and organic ligands used, and a review pays special attention to the examples which show magnetic slow relaxation.
Journal ArticleDOI

A 48‐Metal Cluster Exhibiting a Large Magnetocaloric Effect

TL;DR: The next generation of scientists and researchers will have to consider using nanofiltration membranes for the recovery of phosphorous with a second type of technology called a “computational surrogacy”.
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A Chiral 60-Metal Sodalite Cage Featuring 24 Vertex-Sharing [Er4(μ3-OH)4] Cubanes

TL;DR: A chiral, cagelike, high-nuclearity lanthanide hydroxide cluster containing 60 Er(III) ions is reported, which possesses a fascinating sodalite-like structure with 24 vertex-sharing cubane-like [Er(4)(mu(3)-OH)(4)](8+) units.
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Design and synthesis of 3d-4f metal-based zeolite-type materials with a 3D nanotubular structure encapsulated "water" pipe.

TL;DR: A nanotubular 3D heterometallic zeolitic polymer was designed and synthesized by simply tuning the amount of coordinated water on the Mn ion in the molecular ladder polymer.
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Initial observation of magnetization hysteresis and quantum tunneling in mixed manganese-lanthanide single-molecule magnets.

TL;DR: The Dy compound has been found to give out-of-phase AC susceptibility signals, suggesting it might be a single-molecule magnet (SMM), which is the initial demonstration of hysteresis and quantum behavior in a mixed 3d/4f SMM.
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