A Negative Effect of Co-solvent on Atrazine Biodegradation in Experimental River Microcosms
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In this paper, a 0.1% concentration of acetonitrile as a co-solvent greatly suppressed the microbial degradation of herbicide atrazine [2-chloro-4-(ethylamino)-6-(isopropylamino]-s-triazine] throughout the experimental period (84 days).Abstract:
A water-miscible solvent, such as acetone, acetonitrile or methanol, is often employed as a co-solvent to dissolve an organic test chemical of low water solubility in an environmental fate study using a laboratory model microcosm. These co-solvents, however, may disrupt the microflora in the water/sediment tested, and affect the biodegradation of the target compound. In the present study, a 0.1% concentration of acetonitrile as a co-solvent greatly suppressed the microbial degradation of herbicide atrazine [2-chloro-4-(ethylamino)-6-(isopropylamino)-s-triazine] throughout the experimental period (84 days). The rapid growth of specific microbes was considered to deprive atrazine-degrading microbes of their habitat (mainly the surface area of sediment particles) in the microcosm.read more
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References
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Journal ArticleDOI
Degradation and mineralization of atrazine by a soil bacterial isolate.
TL;DR: This is the first report of a pure bacterial isolate with the ability to cleave the s-triazine ring structure of atrazine, and it was concluded that this bacterium was capable of dealkylation, dechlorination, and deamination in addition to ring cleavage.
Journal ArticleDOI
s-Triazines as nitrogen sources for bacteria
Alasdair M. Cook,Ralf Hütter +1 more
TL;DR: In this paper, three strains of Pseudomonas (A, D, and F) and two strains of Klebsiella pneumoniae (90 and 99) were examined, and specific growth rates with s-triazines were similar to those with ammonium ion as the nitrogen source.
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Degradation of atrazine by Pseudomonas: N-dealkylation and dehalogenation of atrazine and its metabolites
Ram M. Behki,Shahamat U. Khan +1 more
Journal ArticleDOI
Degradation of atrazine in estuarine water/sediment systems and soils.
Journal ArticleDOI
Ring cleavage and degradative pathway of cyanuric acid in bacteria.
TL;DR: Data indicate that the same pathway occurred in another pseudomonad and a strain of Klebsiella pneumoniae, and each substrate was entirely metabolized concomitantly with growth.