Journal ArticleDOI
A Stable Crystalline Carbene.
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This article is published in ChemInform.The article was published on 1991-04-16. It has received 85 citations till now. The article focuses on the topics: Carbene.read more
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Extending NHC-Catalysis: Coupling Aldehydes with Unconventional Reaction Partners
TL;DR: An efficient intermolecular Stetter reaction is developed for the formation of α-amino acid derivatives, with broad aldehyde scope and high enantiomeric excess, and tailor-made thiazolylidene catalysts allowed the unprecedented use of nonactivated olefins and alkynes as aldehydes coupling partners.
Journal ArticleDOI
Polymerization of Ethylene Oxide, Propylene Oxide, and Other Alkylene Oxides: Synthesis, Novel Polymer Architectures, and Bioconjugation.
Jana Herzberger,Kerstin Niederer,Hannah Pohlit,Jan Seiwert,Matthias Worm,Matthias Worm,Frederik R. Wurm,Holger Frey +7 more
TL;DR: With the ever growing toolbox for epoxide polymerization, a "polyether universe" may be envisaged that in its structural diversity parallels the immense variety of structural options available for polymers based on vinyl monomers with a purely carbon-based backbone.
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Ultra stable self-assembled monolayers of N-heterocyclic carbenes on gold
Cathleen M. Crudden,J. Hugh Horton,Iraklii I. Ebralidze,Olena V. Zenkina,Alastair B. McLean,Benedict Drevniok,Zhe She,Heinz-Bernhard Kraatz,Nicholas J. Mosey,Tomohiro Seki,Eric C. Keske,Joanna D. Leake,Alexander Rousina-Webb,Gang Wu +13 more
TL;DR: The generation of N-heterocyclic carbene (NHC)-based SAMs on gold that demonstrate considerably greater resistance to heat and chemical reagents than the thiol-based counterparts are described.
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Formation of water-soluble pincer silver(I)-carbene complexes: a novel antimicrobial agent.
Abdulkareem Melaiye,Richard S. Simons,Amy Milsted,Francesco Pingitore,Chrys Wesdemiotis,Claire A. Tessier,Wiley J. Youngs +6 more
TL;DR: The bactericidal activities of the water-soluble silver(I)-carbene complexes were found to be improved over that of silver nitrate.
References
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A stable crystalline carbene
TL;DR: Synthese, structure et caracterisation du (1,3-bis [1-adamantyl]-2, 3-dihydro)-2,carbenoimidazole prepare par deprotonation du chlorure de (1 3-bis] [1]- imidazolium as discussed by the authors.