Journal ArticleDOI
A Stereocontrolled Access to (±)‐, (−)‐, and (+)‐Patchouli Alcohol
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The racemate and enantiomers of patchouli alcohol have been synthesized by stereocontrolled routes as mentioned in this paper, and the olfactive properties of the patches are reported.Abstract:
The racemate and both enantiomers of patchouli alcohol have been synthesized by stereocontrolled routes. The olfactive properties of the patchouli alcohols prepared are reported.read more
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Enantioselective perception of chiral odorants
TL;DR: Sigler as mentioned in this paper gave an updated account on the phenomena of enantioselective perception of chiral fragrances employed in fine and functional perfumery, and of some selected flavors.
Journal ArticleDOI
Industrial applications of the Diels-Alder reaction.
TL;DR: The Diels-Alder reaction is one of the most popular transformations for organic chemists to generate molecular complexity efficiently, with a focus on large-scale applications (>1 kg) from a process research and development perspective.
Journal ArticleDOI
The diverse sesquiterpene profile of patchouli, Pogostemon cablin, is correlated with a limited number of sesquiterpene synthases
Fabienne Deguerry,Laurence Pastore,Shuiqin Wu,Anthony J. Clark,Joseph Chappell,Michel Schalk +5 more
TL;DR: Interestingly, the yield of the different in vitro reaction products resembles quantitatively and qualitatively the profile of sesquiterpenes found in patchouli oil extracted from plants, suggesting that a single terpene synthase is responsible for the bulk and diversity of terPene products produced in planta.
Journal ArticleDOI
Chemistry of odor stimuli.
TL;DR: The present state of the molecular basis of olfaction is shown and with the aid of various examples the regioselectivity of odor sensation is proven.
References
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Intramolecular [4+2] and [3+2] Cycloadditions in Organic Synthesis
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A total synthesis of lasalocid A
Journal ArticleDOI
Intramolekulare [4 + 2]‐ und [3 + 2]‐Cycloadditionen in der organischen Synthese
TL;DR: In this article, a number of beispiele intramolekularer cycloadditionen of 1,3-Dienen, Nitronen, and Azomethiniminen bezeugen den praparativen Werts zur regio-and stereoselektiven Synthese anellierter sowie uberbruckter Ringsysteme.