Journal ArticleDOI
A thermodynamic study of bivalent metal halides in aqueous solution
R. A. Robinson,R. H. Stokes +1 more
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This article is published in Transactions of The Faraday Society.The article was published on 1940-01-01. It has received 49 citations till now. The article focuses on the topics: Aqueous solution & Metal halides.read more
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Critical Evaluation of the Thermodynamic Properties of Aqueous Calcium Chloride. 1. Osmotic and Activity Coefficients of 0−10.77 mol·kg-1 Aqueous Calcium Chloride Solutions at 298.15 K and Correlation with Extended Pitzer Ion-Interaction Models
Joseph A. Rard,Simon L. Clegg +1 more
TL;DR: In this paper, isopiestic vapor pressure measurements were performed at 298.15 K for CaCl2(aq) solutions at 66 molalities from (4.3235 to 10.253) mol·kg-1, with emphasis given to the accurate characterization of the osmotic coefficients near and above saturation.
Journal ArticleDOI
Activity Coefficients in Concentrated Solutions Containing Several Electrolytes
TL;DR: In this paper, a method for the determination of the activity coefficients of the separate salts in mixtures is proposed, which is a major experimental difficulty, and it is desirable to have a method to calculate their coefficients.
Journal ArticleDOI
Thermodynamics of aqueous calcium chloride
TL;DR: In this paper, various published measurements of the osmotic coefficient and the apparent molal enthalpy of aqueous CaCl2 are examined and correlated and the anomalous behavior near 5 molal is discussed.
Journal ArticleDOI
Crystalline and Liquid Structure of Zinc Chloride Trihydrate: A Unique Ionic Liquid
Robert J. Wilcox,Bradley P. Losey,Jacob C. W. Folmer,James D. Martin,Matthias Zeller,Roger D. Sommer +5 more
TL;DR: The water/ZnCl(2) phase diagram in the vicinity of the 75 mol % water composition is reported, demonstrating the existence of a congruently melting phase and a novel nonpolar, hydrogen-bonding, ionic liquid solvent.
Journal ArticleDOI
Phase Behavior of Aqueous Na–K–Mg–Ca–Cl–NO3 Mixtures: Isopiestic Measurements and Thermodynamic Modeling
TL;DR: In this paper, a comprehensive model has been established for calculating thermodynamic properties of multicomponent aqueous systems containing the Na+, K+, Mg2+, Ca2+, Cl− and NO 3 − ions.
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