Journal ArticleDOI
Additions of Organometallic Reagents to C=N Bonds: Reactivity and Selectivity
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This article is published in Chemical Reviews.The article was published on 1998-06-03. It has received 796 citations till now. The article focuses on the topics: Reactivity (chemistry).read more
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Catalytic enantioselective addition to imines.
Shu Kobayashi,Haruro Ishitani +1 more
TL;DR: Shū Kobayashi was born in 1959 in Tokyo, Japan and studied chemistry at the University of Tokyo and received his Ph.D. in 1988 (Professor T. Mukaiyama), and received the first Springer Award in Organometallic Chemistry in 1997.
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Transition Metal-Catalyzed Decarboxylative Allylation and Benzylation Reactions
TL;DR: Transition metal catalyzed decarboxylative allylation, benzylations, and interceptive allylations are reviewed.
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Catalytic Enantioselective Formation of C−C Bonds by Addition to Imines and Hydrazones: A Ten-Year Update
References
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Journal ArticleDOI
Allylic 1,3-strain as a controlling factor in stereoselective transformations
TL;DR: In this article, the authors present a model for controlling dyadic add-ion reactions to double-branched double-bond reactions, including the following: 1.3-Strain Control of Dlastereoselective Intermolecular Addhion Reactions InvoMng Heteroallyl Systems 10.5.
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Chelation or Non‐Chelation Control in Addition Reactions of Chiral α‐ and β‐ Alkoxy Carbonyl Compounds [New Synthetic Methods (44)]
TL;DR: In this article, two strategies have been developed: (1) Use of Lewisacidic reagents which form intermediate chelates, these being attacked stereoselectively from the less hindered side (chelation control); (2) use of reagents incapable of chelation, stereoselection attack being governed by electronic and/or steric factors (non-chelation Control).
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Reactions of carbonyl compounds with Grignard reagents in the presence of cerium chloride
TL;DR: The addition of Grignard reagents to ketones is significantly enhanced by cerium chloride with remarkable suppression of side reactions, particularly enolization.
Journal ArticleDOI
Catalytic reduction of carbon dioxide at carbon electrodes modified with cobalt phthalocyanine
TL;DR: In this article, Hoffmann et al. showed that the bad interactions depicted in 9 and 16 can be avoided by rotating the carbon so that the hydrogen is in the position of the methyl in 9, and the phenyl in 16.
Related Papers (5)
Asymmetric synthesis of amines by nucleophilic 1,2-addition of organometallic reagents to the CN-double bond
Dieter Enders,Ulrich Reinhold +1 more