Adsorption, separation, and catalytic properties of densified metal-organic frameworks
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TLDR
In this article, the properties and applications of densified metal-organic frameworks with different metal clusters and organic linkers are discussed, as well as the methods that increase the packing density in MOFs (for example, intentional interpenetration, etc.).About:
This article is published in Coordination Chemistry Reviews.The article was published on 2016-03-15 and is currently open access. It has received 256 citations till now. The article focuses on the topics: Adsorption & Porosity.read more
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CO2 Capture and Separations Using MOFs: Computational and Experimental Studies
TL;DR: This Review focuses on research oriented toward elucidation of the various aspects that determine adsorption of CO2 in metal-organic frameworks and its separation from gas mixtures found in industrial processes.
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Robust and conductive two-dimensional metal−organic frameworks with exceptionally high volumetric and areal capacitance
Dawei Feng,Ting Lei,Maria R. Lukatskaya,Jihye Park,Zhehao Huang,Minah Lee,Leo Shaw,Shucheng Chen,Andrey A. Yakovenko,Ambarish Kulkarni,Jianping Xiao,Kurt Fredrickson,Jeffrey B.-H. Tok,Xiaodong Zou,Yi Cui,Zhenan Bao +15 more
TL;DR: In this article, a highperforming electrode based on conductive hexaaminobenzene (HAB)-derived two-dimensional metal-organic frameworks (MOFs) is reported.
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Metal-organic frameworks for highly efficient heterogeneous Fenton-like catalysis
Min Cheng,Cui Lai,Yang Liu,Guangming Zeng,Danlian Huang,Chen Zhang,Lei Qin,Liang Hu,Chengyun Zhou,Weiping Xiong +9 more
TL;DR: The use of metal-organic frameworks (MOFs) or MOF composites as catalysts for Fenton-like catalysis has received increasing attention due to their permanent porosity and tunable open metal centers as mentioned in this paper.
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Applications of metal-organic frameworks in adsorption/separation processes via hydrogen bonding interactions
Imteaz Ahmed,Sung Hwa Jhung +1 more
TL;DR: In this paper, a review of hydrogen bonding interactions between metal-organic frameworks and adsorbates is presented, which will motivate the development of methods and techniques to utilize hydrogen bonding in several important adsorption-based applications of MOFs.
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Metal-Organic Frameworks against Toxic Chemicals
Timur Islamoglu,Zhijie Chen,Megan C. Wasson,Cassandra T. Buru,Kent O. Kirlikovali,Unjila Afrin,Mohammad Rasel Mian,Omar K. Farha +7 more
TL;DR: This review will focus on recent advancements in MOF-based adsorbent design for protection against chemical warfare agents and toxic industrial chemicals such as H2S, NH3, SO2, CO, NO2, and NO.
References
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The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
TL;DR: Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Metal–Organic Framework Materials as Chemical Sensors
Lauren E. Kreno,Kirsty Leong,Omar K. Farha,Mark D. Allendorf,Richard P. Van Duyne,Joseph T. Hupp +5 more
TL;DR: The potential to computationally predict, with good accuracy, affinities of guests for host frameworks points to the prospect of routinely predesigning frameworks to deliver desired properties.
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Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
Kyo Sung Park,Zheng Ni,Adrien P. Côté,Jae Yong Choi,Rudan Huang,Fernando J. Uribe-Romo,Hee K. Chae,Michael O'Keeffe,Omar M. Yaghi +8 more
TL;DR: Study of the gas adsorption and thermal and chemical stability of two prototypical members, ZIF-8 and -11, demonstrated their permanent porosity, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvents.
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