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Alkali-Activated Materials and Geopolymer: a Review of Common Precursors and Activators Addressing Circular Economy

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TLDR
In this paper, the authors reviewed different types, mechanisms, and result of mechanical and durability properties of alkali-activated materials and geopolymer reported in literature and discussed future projections of waste materials that have cementitious properties and can replace ordinary Portland cement and be used in alkali activated materials.
Abstract
The vast increase in CO2 and waste generation in recent decades has been a major obstacle to sustainable development and sustainability. In construction industry, the production of ordinary Portland cement is a major greenhouse gas emitter with almost 8% of total CO2 production in the world. To address this, Alkali-activated materials and geopolymer have more recently been introduced as a green and sustainable alternative of ordinary Portland cement with significantly lowered environmental footprints. Their use to replace Portland cement products generally leads to vast energy and virgin materials savings resulting in a sustainable concrete production. In doing so, it reuses the solid waste generated in industrial and manufacturing sectors, which is aligned with circular economy. In turn, it reduces the need for ordinary Portland cement consumption and its subsequent CO2 generation. To provide further insight and address the challenges facing the substitution of ordinary Portland cement, this article reviews different types, mechanisms, and result of mechanical and durability properties of alkali-activated materials and geopolymer reported in literature. Finally, it discusses future projections of waste materials that have cementitious properties and can replace ordinary Portland cement and be used in alkali-activated materials and geopolymer.

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Journal ArticleDOI

Fire resistance of geopolymer concrete: A critical review

TL;DR: In this paper , a critical literature review of current updates related to the fire performance of RF-reinforced GPC subjected to elevated temperatures and during fires is urgently necessary, conducting critical reviews on the type of RFs, spalling mechanism, physical inspection and properties of the RF-RGPCs.
Journal ArticleDOI

Sustainable concrete for circular economy: a review on use of waste glass

TL;DR: In this article, the connection of construction sector and circular economy with recycled glass in its center is reviewed, and it is shown that by partially replacing Portland cement or aggregate with recycling glass, on average, up to 19% greenhouse gas and 17% energy consumption reduction as well as major cost savings can be made.
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A comparative review on foam-based versus lightweight aggregate-based alkali-activated materials and geopolymer

TL;DR: In this paper, the authors provide an updated information on recent advances while stressing the sustainability of lightweight geopolymer materials over ordinary Portland cement products that are vastly in use, including perlite, pumice, shale, ceramsite, and slate sand.
Journal ArticleDOI

Fresh, mechanical and microstructural properties of alkali-activated composites incorporating nanomaterials: A comprehensive review

TL;DR: In this paper , nano-modified alkali-activated composites (AACs) or geopolymers have attracted attention owing to their excellent performance and modification mechanisms, and the results mostly indicated that while increasing nano-additives proportion to a certain extent improves the mechanical characteristics, including compressive, flexural, tensile, and impact strengths, incorporation beyond that amount deteriorates them.
Journal ArticleDOI

The effect of curing regimes on physico-mechanical, microstructural and durability properties of alkali-activated materials: A review

TL;DR: In this article , the most commonly used curing regimes for AAMs are conducted in thermal or ambient temperature environments, adopted in the form of immersion of the AAM in water, ambient and high humidity, sealing, oven and, more recently, microwave curing.
References
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Journal ArticleDOI

Geopolymer synthetized from bottom coal ash and calcined paper sludge

TL;DR: In this article, bottom ash (SiO2/Al2O3) was used as source of aluminosilicate and sodium hydroxide (NaOH = 5, 10 and 15 m) and sodium silicate (Na2SiO3, SiO2 /Na2O= 1.58) were used as alkaline medium.
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Alkali-activated Portland blast-furnace slag cement: Mechanical properties and hydration

TL;DR: In this article, the kinetic, the mechanical development and the microstructure of an alkali-activated blended Portland cement produced from the mixture of a granulated blast furnace slag and Portland cement in proportion 80% and 20% respectively were studied.
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Lightweight geopolymer made of highly porous siliceous materials with various Na2O/Al2O3 and SiO2/Al2O3 ratios

TL;DR: In this article, the effects of fineness and calcination temperature of diatomaceous earth (DE), concentrations of NaOH and KOH, DE to RHA ratio; curing temperature and time on the mechanical properties and microstructures of the geopolymer pastes were investigated.
Journal ArticleDOI

Properties and characterization of green one-part geopolymer activated by composite activators

TL;DR: In this article, the Na2CO3 was used to replace a portion of Na2SiO3-anhydrous, and the properties of one-part geopolymer with composite activators were investigated systematically.
Journal ArticleDOI

Performance of refractory aluminosilicate particle/fiber-reinforced geopolymer composites

TL;DR: In this paper, the authors assess the mechanical performance of metakaolin-based geopolymers reinforced with refractory aluminosilicate particles and fibers, after exposure to elevated temperatures.
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