Patent
Allene thiocyanide derivative and synthesis method thereof
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TLDR
In this article, an allene thiocyanide derivative and a synthesis method of the derivative were presented. But the synthesis method was based on a two-step tandem reaction at room temperature to obtain the derivative, which has the advantages of simple operation, safety, high efficiency, mild condition and the like.Abstract:
The invention discloses an allene thiocyanide derivative and a synthesis method thereof. Propargylamine and trifluoromethylthio silver are used as raw materials, a haloid is used as an additive, an organic solvent is used as a solvent, and a two-step tandem reaction is carried out at room temperature to obtain the allene thiocyanide derivative. The synthesis method of the allene thiocyanide derivative has the advantages of simple operation, safety, high efficiency, mild condition and the like.read more
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Synthesis methods for isothiocyanate derivative
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Journal ArticleDOI
Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra‐n‐butylammonium Iodide
TL;DR: An unprecedented reaction for the direct trifluoromethylthiolation and fluorination of alkyl alcohols using AgSCF3 and nBu4NI has been developed and is tolerant of different functional groups.
Journal ArticleDOI
Synthesis of New Vinyl Thiocyanates by [3,3] Sigmatropic Rearrangement of Isothiocyanates
TL;DR: In this article, it was shown that the sigmoid rearrangement of mustard oils, to afford high yields of thiocyanates bearing the thermodynamically less stable functional group, is possible if the conversion gives rise to a more stable carbon skeleton.
Patent
Biocidal allene thiocyanates
TL;DR: In this paper, the general formula R R C=C=CR SCN can be used as biocides against both bacteria and fungi and can be applied as cutting fluid preservative, a wood preservative in cooling water applications or as an antimicrobial agent in a paint.