Journal ArticleDOI
Allylic and propargylic imidic esters in organic synthesis
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This article is published in Accounts of Chemical Research.The article was published on 1980-07-01. It has received 191 citations till now. The article focuses on the topics: Allylic rearrangement & Organic synthesis.read more
Citations
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New Methods for the Synthesis of Glycosides and Oligosaccharides—Are There Alternatives to the Koenigs‐Knorr Method? [New Synthetic Methods (56)]
TL;DR: Emphasis is placed on glycoside and saccharide formation by 1-O-alkylation, on the trichloroacetimidate method, and on activation through the formation of glycosylsulfonium salts and Glycosyl fluorides.
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Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications
TL;DR: Enantioselective PdII-catalyzed functionalization of alkenes has experienced considerably less success than have many other classes of enantiOSElective transformations, despite the extensive history of the Wacker process and related oxidation reactions.
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C-H activation: a complementary tool in the total synthesis of complex natural products.
David Y.-K. Chen,So Won Youn +1 more
TL;DR: Recently completed total syntheses showcasing creative and ingenious incorporation of C-Hactivation as a strategic manoeuver are compared with their "non-C-H activation" counterparts, illuminating a new paradigm in strategic synthetic design.
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Neue Methoden zur Glycosid- und Oligosaccharidsynthese – gibt es Alternativen zur Koenigs-Knorr-Methode?
TL;DR: Glycoproteine, Glycolipide and Glycophospholipide (=Glycokonjugate) sind Bestandteile von Membranen.
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Chiral NHC–metal-based asymmetric catalysis
TL;DR: In this paper, the growing field of chiral NHC-metal-based asymmetric catalysis is comprehensively described, and strategies for the design of efficient N-heterocyclic carbenes and novel asymmetric synthetic methodologies have dramatically increased over the past 10 years.
References
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Catalytic irreversible inhibition of mammalian ornithine decarboxylase (E.C.4.1.1.17) by substrate and product analogs
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Intramolecular [4+2] and [3+2] Cycloadditions in Organic Synthesis
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Energies and alkylations of tautomeric heterocyclic compounds: old problems - new answers
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A general method for the synthesis of amines by the rearrangement of allylic trichloroacetimidates. 1,3 Transposition of alcohol and amine functions
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Macrolides. Recent progress in chemistry and biochemistry.
TL;DR: This review attempts to cover the important contributions which have been made in the fields of structural and synthetic chemistry as well as in the biosynthesis and mode of antimicrobial activity of the “polyoxo” macrolide antibiotics.