Journal ArticleDOI
An Unusually Fast Nucleophilic Aromatic Displacement Reaction: The Gas‐Phase Reaction of Fluoride Ions with Nitrobenzene
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This article is published in Angewandte Chemie.The article was published on 2004-07-05. It has received 69 citations till now. The article focuses on the topics: Nucleophilic aromatic substitution & Substitution reaction.read more
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Journal ArticleDOI
Room-temperature nucleophilic aromatic fluorination: experimental and theoretical studies.
Haoran Sun,Stephen G. DiMagno +1 more
Journal ArticleDOI
Concerted nucleophilic aromatic substitutions
TL;DR: New and sensitive methodology for measuring carbon kinetic isotope effects now shows that most such substitutions actually occur through concerted mechanisms.
Journal ArticleDOI
Rate-Determining Factors in Nucleophilic Aromatic Substitution Reactions
TL;DR: Increased stability, and thereby increased intrinsic nucleophilicity, correlates with decreasing aromatic character of the Meisenheimer structure, explained in consistency with the other observations using the same model.
Journal ArticleDOI
Concerted Nucleophilic Aromatic Substitution Reactions.
Simon Rohrbach,Andrew J. Smith,Jia Hao Pang,Darren L. Poole,Tell Tuttle,Shunsuke Chiba,John A. Murphy +6 more
TL;DR: This work has identified a rapidly growing class of nucleophilic aromatic substitutions that proceed by concerted (cSNAr) rather than classical, two‐step, SNAr mechanisms.
Journal ArticleDOI
Atmospheric pressure ion/molecule reactions for the selective detection of nitroaromatic explosives using acetonitrile and air as reagents.
Yishu Song,R. Graham Cooks +1 more
TL;DR: DAPCI is demonstrated to be a useful ambient detection method for nitroaromatic explosives absorbed on surfaces because their different chemistry facilitates analyte identification.
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Room-temperature nucleophilic aromatic fluorination: experimental and theoretical studies.
Haoran Sun,Stephen G. DiMagno +1 more