Journal ArticleDOI
Aquation and base hydrolysis of nitratopentaamminerhodium(III) and -iridium(III) complexes
Fabrizio Monacelli,S. Viticoli +1 more
TLDR
In this article, the acid and base hydrolysis of nitratopentaamminerhodium (III) and iridium(III) cations have been studied kinetically and the observed rate constants were found to follow the equation k obs = k aq + k OH [OH − ].About:
This article is published in Inorganica Chimica Acta.The article was published on 1973-01-01. It has received 6 citations till now. The article focuses on the topics: Aquation & Standard molar entropy.read more
Citations
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Journal ArticleDOI
Activation parameters and reaction mechanism in octahedral substitution
Journal ArticleDOI
A review of platinum metal nitrato complexes
Journal ArticleDOI
Mechanistic studies on rhodium(iii) chelates. aquation of cis‐dihalobisbiguaniderhodium(iii) nitrates
Biswanath Chakravarty,A.K. Sil +1 more
TL;DR: In this article, the first and second halide ions were derived by a graphical method and the rates of release of the first ion and second ion were derived using the Eyring equation.
Journal ArticleDOI
Kinetics of ammoniation of some halobis(ethylenediamine)-rhodium(III) perchlorates in liquid ammonia
Sijbe Balt,Andries Jelsma +1 more
TL;DR: In this article, the ammoniation of cis-[Rh(en)2Cl2] · (ClO4) in liquid NH3 was studied at constant ionic medium of 0.20 m perchlorate in the 0 to 35° range.
Journal ArticleDOI
The saga of rhodium(III) nitrate complexes and their speciation in solution: An integrated experimental and quantum chemical study
Sofia N. Vorobyeva,Nikita A. Shekhovtsov,I. A. Baidina,Taisiya S. Sukhikh,Sergey V. Tkachev,Mark B. Bushuev,A. V. Belyaev +6 more
TL;DR: In this article, a series of soluble rhodium(III) nitrate complexes with four and five coordinated NO3− ligands were synthesized by equilibrated solutions of a "rhodium nitrate solution" with (CH3)4NNO3 and (C2H5)4N.
References
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Journal ArticleDOI
Effect of Temperature, Pressure, Acidity and Solvent on an Aquo Ion Exchange Reaction
H. R. Hunt,H. Taube +1 more
Journal ArticleDOI
Acid catalysis of the hydrolysis of acetato-pentammine complexes of cobalt(III), rhodium(III) and iridium(III)
TL;DR: In this article, the synthesis of [M(NH3)5(RCOO)](ClO4)2 where M = Rh(III) or Ir(III), and RCOO− = CH3COO−, (CH3)3CCOO− or CF3cOO− are described.
Journal ArticleDOI
The exchange reaction between [Rh(NH3)5OH2]3+ and solvent water
Fabrizio Monacelli,E. Viel +1 more
TL;DR: In this paper, the water exchange reaction of [Rh(NH 3 ) 5 OH 2 ] 3+ ion has been kinetically studied by means of an 18 O tracer technique, and rates were found to be independent of pH and addition of NaCl.
Related Papers (5)
The acid and base hydrolysis of sulfatopentamminecobalt(III) and rhodium(III) complexes
Kinetics of aquation and base hydrolysis of cis bioxaltoammine bis(ethylenediamine) cobalt(III) ion
Anadi C. Dash,R.K. Nanda +1 more