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Assessment of nanocomposite photonic systems with the X-ray photoelectron spectroscopy

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TLDR
In this article, the chemical compositions of Ag-Er co-doped phosphate and silicate glasses were investigated with X-ray photoelectron spectroscopy with the purpose to identify the chemical state of silver.
Abstract
The chemical compositions of Ag-Er co-doped phosphate and silicate glasses were investigated with X-ray photoelectron spectroscopy with the purpose to identify the chemical state of silver. The analysis of the Ag 3d core lines show the presence of nanometer-sized silver particles in each of the annealed samples, even if these Ag 3d lines appear to be very different from each other. We explain these results as a different interaction of silver with the two glasses matrix, which leads to a different nucleation rate of the Ag clusters.

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Journal ArticleDOI

Electronic structure of supported small metal clusters

TL;DR: In this article, the degree of cluster-support interaction for clusters of group-VIII and noble metals can be divided into two categories: supports with localized $p$ or $d$ orbitals with binding energies overlapping those of the cluster $d $ orbitals and supports without such orbitals.
Journal ArticleDOI

The optical kerr effect in small metal particles and metal colloids: The case of gold

TL;DR: In this paper, the authors considered theoretically the various mechanisms contributing to the Kerr nonlinearity in small gold particles, including conduction electron intraband contribution, saturation of direct interband transitions and the change in dielectric constant due to hot photoexcited electrons.
Journal ArticleDOI

Field enhancement effect of small Ag particles on the fluorescence from Eu3+-doped SiO2 glass

TL;DR: In this article, the effects of nanometer-sized silver particles on the optical properties of Eu3+ ions in SiO2 glass were investigated by using Mie-Drude theory modified by electron mean free path model.
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