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Atomic and molecular spin-orbit coupling constants for 3d transition metal ions
G. Mattney Cole,Barry B. Garrett +1 more
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This article is published in Inorganic Chemistry.The article was published on 1970-08-01. It has received 69 citations till now. The article focuses on the topics: Metal L-edge & Metal K-edge.read more
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Systematics of the breakdown of Mott insulation in binary transition metal compounds
TL;DR: In this paper, an attempt has been made to illuminate the intricacies of the Mott transition as applicable to binary transition metal compounds, and the properties of materials close to either side of the transition are discussed.
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Design and Control of the Luminescence of Cr3+-Doped Phosphors in the Near-Infrared I Region by Fitting the Crystal Field
TL;DR: In this paper, a red phosphor with a broad emission band was designed and realized tunable luminescence of Cr3+ by two methods, i.e., adjusting the Cr3-doping concentration in Zn3(AlGa)2Ge2O10 solid solution and doping In3+ ions in ZN3Al2Ge 2O10 due to a size mismatch.
Journal ArticleDOI
Investigation of mechanism of nephelauxetic effect
Faming Gao,Siyuan Zhang +1 more
TL;DR: By using the chemical bond theory of dielectric description and electronic structure of 3D elements, the mechanism of nephelauxetic effect is studied, and the main factors responsible for this effect are identified as mentioned in this paper.
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Redox-Active Bis(phenolate) N-Heterocyclic Carbene [OCO] Pincer Ligands Support Cobalt Electron Transfer Series Spanning Four Oxidation States
Caleb F. Harris,Michael B. Bayless,Nicolaas P. van Leest,Quinton J. Bruch,Brooke N. Livesay,John Bacsa,John Bacsa,Kenneth I. Hardcastle,Matthew P. Shores,Bas de Bruin,Jake D. Soper +10 more
TL;DR: Combined experimental and computational data suggest that the charge-neutral four-coordinate Co complexes supported by three redox-noninnocent tridentate [OCO] pincer-type bis(phenolate) N-heterocyclic carbene (NHC) ligands are best formulated as Co(II) centers bound to closed-shell [ OCO]2- dianions, of the general formula [(OCO)CoIIL]